Was Bijvoet right? Sodium rubidium (+)-tartrate tetrahydrate revisited

被引：10

作者：

Lutz, Martin ^{[1
]}

Schreurs, Antoine M. M. ^{[1
]}

机构：

[1] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, Fac Sci, NL-3584 CH Utrecht, Netherlands

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2008年 / 64卷 / 08期

关键词：

D O I：

10.1107/S0108270108022415

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first determination of the absolute configuration of an organic compound was published in 1951 on sodium rubidium (+)-tartrate tetrahydrate, Na+center dot Rb+center dot C4H4O62-center dot 4H(2)O, but the atomic coordinates are not available in the public literature. This structure has therefore been redetermined using current equipment. The most up-to-date techniques for the determination of the absolute configuration have been applied and the question posed in the title can be answered with an unequivocal 'yes'.

引用

页码：M296 / M299

页数：4

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