Volumetric and viscous behaviour of the binary and ternary systems formed by methyl acetate, ethyl acetate and 1-propanol at 283.15, 298.15 and 313.15 K

被引:12
作者
Canzonieri, Salvador [2 ]
Camacho, Alberto [1 ]
Tabarrozzi, Ruben [3 ]
Postigo, Miguel [1 ]
Mussari, Lelia [1 ]
机构
[1] Univ Nacl Comahue, Fac Ingn, Dept Quim, Neuquen, Argentina
[2] Univ Nacl Comahue, Fac Ingn, Dept Fis, Neuquen, Argentina
[3] Univ Nacl Comahue, Fac Ingn, Dept Electrotecnia, Neuquen, Argentina
关键词
density; viscosity; excess molar volume; methyl acetate; ethyl acetate; 1-propanol; LIQUID-MIXTURES; VISCOSITY;
D O I
10.1080/00319104.2011.637626
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Experimental data of density and viscosity of the binary and ternary systems formed by methyl acetate, ethyl acetate and 1-propanol are reported here, in the whole range of concentration, at atmospheric pressure and 283.15, 298.15 and 313.15 K. Deviation of viscosity, excess molar volume, thermal expansivity coefficient, excess thermal expansivity coefficient and excess Gibbs energy of activation for viscous flow were calculated from the values of viscosity and density. The results for the binary systems were adjusted to the Redlich-Kister expansion. Cibulka expression was used to adjust ternary system properties. Estimated values of the properties for the ternary system using symmetric geometrical models were compared with experimental results. Katti-Chaudrhi model was applied to evaluate the viscosities of the mixtures and compared with experimental values.
引用
收藏
页码:530 / 545
页数:16
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