Syntheses and crystal structures of Y(HSO4)3-I and Y(HSO4)3 • H2O

被引：0
|
作者：
Wickleder, MS [1 ]
机构：
[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 10期
关键词：
rare earth elements; yttrium; hydrogensulfates; hydrogen bonding;
D O I：
10.1002/(SICI)1521-3749(199910)625:10<1707::AID-ZAAC1707>3.0.CO;2-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Lath shaped crystals of Y(HSO4)-I are obtained by treatment of Y2O3 with conc. sulfuric acid at 200 degrees C. Y(HSO4)(3)-I crystallizes orthorhombic (Pbca, Z = 8, a = 1201.5(1), b = 953.76(8), c = 1650.4(1) pm, R-all = 0.0388). In the crystal structure Y3+ is coordinated by eight monodentate HSO4- groups. Colorless, plate like single crystals of Y(HSO4)(3). H2O grew from a solution of Y2O3 in 85% sulfuric acid upon cooling. In the crystal structure of the tri- clinic compound (P (1) over bar, Z = 2, a = 679.8(1), b = 802.8(2), c = 965.9(2) pm, alpha = 79.99(2)degrees, beta = 77.32(2)degrees, gamma = 77.50(2)degrees, R-all = 0.0264) Y3+ is surrounded by seven HSO4- groups and one molecule of water.
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页码：1707 / 1711
页数：5
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