Self-assembly of amphiphilic random co-poly(ionic liquid)s: the effect of anions, molecular weight, and molecular weight distribution

被引：57
作者：
Guo, Jiangna [1 ]
Zhou, Yinxia [1 ]
Qiu, Lihua [1 ]
Yuan, Chao [1 ]
Yan, Feng [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Dept Polymer Sci & Engn, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Suzhou 215123, Peoples R China
来源：
POLYMER CHEMISTRY | 2013年 / 4卷 / 14期
关键词：
POLYMERIZED IONIC LIQUIDS; DIBLOCK COPOLYMERS; BLOCK-COPOLYMERS; MULTIPLE MORPHOLOGIES; AQUEOUS-SOLUTIONS; EXCHANGE; NANOPARTICLES; MICELLES; VESICLES; ACID);
D O I：
10.1039/c3py00460k
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Self-assembly behavior of amphiphilic random co-poly(ionic liquid)s in aqueous solution was investigated in this work. An imidazolium-type homopolymer, poly(1-(4-vinylbenzyl)-3-methyl imidazolium chloride) (denoted as PIL-[Cl]),was synthesized via reversible addition fragmentation chain transfer (RAFT) polymerization of p-chloromethyl styrene, and followed by post-polymerization with methylimidazole (or vinylimidazole). Partial anion-exchange of PIL-[Cl] with PF6- anions yielded amphiphilic random copolymers, PIL-[Cl](x)[PF6](y) (suffixes x, y represent the relative molar ratio of Cl- and PF6- anions). Self-assembly morphologies of PIL-[Cl](x)[PF6](y) in aqueous solution as a function of copolymer composition (anions), molecular weight, and molecular weight distribution were investigated. The size of well-defined PIL-[Cl](x)[PF6](y) spherical micelles increased dramatically with increasing molecular weight distribution, while the anions and molecular weight show little effect on the micelle size. Furthermore, self-assembly of amphiphilic random ionic copolymers with the vinylimidazole groups yielded colloidosomes, which might be due to the polymerization of vinylimidazole groups.
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收藏
页码：4004 / 4009
页数：6
相关论文
共 50 条
[1]   Vesicles and liposomes:: A self-assembly principle beyond lipids [J].
Antonietti, M ;
Förster, S .
ADVANCED MATERIALS, 2003, 15 (16) :1323-1333
[2]   The effect of cation structure on the mesophase architecture of self-assembled and polymerized imidazolium-based ionic liquids [J].
Batra, Dolly ;
Seifert, Sonke ;
Firestone, Millicent A. .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2007, 208 (13) :1416-1427
[3]   Influence of Anion Exchange in Self-Assembling of Polymeric Ionic Liquid Block Copolymers [J].
Carrasco, Pedro Maria ;
de Luzuriaga, Alaitz Ruiz ;
Constantinou, Marios ;
Georgopanos, Prokopios ;
Rangou, Sofia ;
Avgeropoulos, Apostolos ;
Zafeiropoulos, Nikolaos E. ;
Grande, Hans-Jurge ;
Cabanero, German ;
Mecerreyes, David ;
Garcia, Ignacio .
MACROMOLECULES, 2011, 44 (12) :4936-4941
[4]   Polymerized Ionic Liquids: Solution Properties and Electrospinning [J].
Chen, Hong ;
Elabd, Yossef A. .
MACROMOLECULES, 2009, 42 (09) :3368-3373
[5]   Phase Behavior and Photoresponse of Azobenzene-Containing Polystyrene-block-poly(n-butyl methacrylate) Block Copolymers [J].
Chen, Wei ;
Wei, Xinyu ;
Balazs, Anna C. ;
Matyjaszewski, Krzysztof ;
Russell, Thomas P. .
MACROMOLECULES, 2011, 44 (05) :1125-1131
[6]   Vesicular assembly and thermo-responsive vesicle-to-micelle transition from an amphiphilic random copolymer [J].
Dan, Krishna ;
Bose, Nivedita ;
Ghosh, Suhrit .
CHEMICAL COMMUNICATIONS, 2011, 47 (46) :12491-12493
[7]   Basic ionic liquids: a new type of ligand and catalyst for the AGET ATRP of methyl methacrylate [J].
Deng, Zhijun ;
Guo, Jiangna ;
Qiu, Lihua ;
Zhou, Yinxia ;
Xia, Lin ;
Yan, Feng .
POLYMER CHEMISTRY, 2012, 3 (09) :2436-2443
[8]   Ionic liquid (molten salt) phase organometallic catalysis [J].
Dupont, J ;
de Souza, RF ;
Suarez, PAZ .
CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691
[9]  
Forster S., 2002, Angew. Chem, V114, P712, DOI DOI 10.1002/1521-3757(20020301)114:5<LESSTHAN>712::AID-ANGE712<GREATERTHAN>3.0.CO
[10]  
2-V
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