Importance of Specific Heat Characterization when Reporting New Superconductors: An Example of Superconductivity in LiGa2Rh

被引:20
作者
Carnicom, Elizabeth M. [1 ]
Xie, Weiwei [2 ]
Yang, Zoe [1 ]
Gornicka, Karolina [3 ]
Kong, Tai [1 ]
Klimczuk, Tomasz [3 ]
Cava, Robert J. [1 ]
机构
[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
[2] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA
[3] Gdansk Univ Technol, Dept Phys, PL-80233 Gdansk, Poland
关键词
TOTAL-ENERGY CALCULATIONS; HEUSLER ALLOY; TRANSITION-TEMPERATURE; TRANSPORT-PROPERTIES; EARTH; COEXISTENCE; MAGNETISM; COMPOUND; CRYSTAL;
D O I
10.1021/acs.chemmater.9b00258
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We show that the full-Heusler compound LiGa2Rh is a superconductor with T-c = 2.4 K. The new superconductor was found as a result of an intuition-based extension of a database search for superconductors that looked for the presence of peaks in the electronic band structure near the Fermi energy. The measurement of the entropy loss during the transition from the nonsuperconducting to the superconducting state, a straightforward measurement rarely presented in reports of "new" superconducting materials, played a critical role in identifying and isolating the superconducting compound. This study presents a particularly good example of how specific heat measurements are important for the identification and isolation of a new superconductor, since much more frequently reported resistive and magnetic susceptibility characterizations are often not enough to confirm the identification of a new superconducting material.
引用
收藏
页码:2164 / 2173
页数:10
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