Thermodynamics for the preparation of micron-sized monodispersed highly monomer-'adsorbed' polymer particles utilizing the dynamic swelling method

被引：8

作者：

Yamashita, T ^{[1
]}

Okubo, M ^{[1
]}

机构：

[1] Kobe Univ, Fac Engn, Dept Sci & Chem Engn, Kobe, Hyogo 6578501, Japan

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1999年 / 153卷 / 1-3期

关键词：

dynamic swelling method; dynamics; micron-size; monomer adsorption; polymer particle;

D O I：

10.1016/S0927-7757(98)00437-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In previous articles, micron-sized monodispersed composite polymer particles were produced by seeded polymerizations for highly monomer-swollen polymer particles, in which the seed particle dissolves, prepared by the dynamic swelling method (DSM) proposed by the authors. This article discusses theoretically the thermodynamic background of DSM with seed particle which does not dissolve in monomer. It was clarified that the preparation of highly monomer-'adsorbed' polymer particles by DSM can be reasonably explained from the viewpoint of thermodynamic treatment under equilibrium and kinetic control states. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：153 / 159

页数：7

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