Nickel-Catalyzed Decarboxylative Coupling of Alkynyl Carboxylates with Aryl Tosylates and Mesylates

被引：5
|
作者：
Howard, Anna [1 ]
Klemann, Samantha [1 ]
Kolling, Sarah [1 ]
Little, Katrina [1 ]
Plasek, Erin [1 ]
Kalyani, Dipannita [1 ]
机构：
[1] St Olaf Coll, Dept Chem, 1520 St Olaf Ave, Northfield, MN 55057 USA
来源：
SYNTHESIS-STUTTGART | 2019年 / 51卷 / 07期
关键词：
alkynes; arenes; carboxylic acids; cross-coupling; nickel catalysis; decarboxylative; C-H ARYLATION; POTASSIUM POLYFLUOROBENZOATES; ALLYL ARYL; ACIDS; PHOTOREDOX; HALIDES; TRANSFORMATIONS; ETHERIFICATION; ALKENYLATION; ACYLATION;
D O I：
10.1055/s-0037-1609636
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A method for the nickel-catalyzed coupling of alkynyl carboxylates or acids with aryl tosylates and mesylates is described. Electronically varied carboxylates and aryl electrophiles participate in these transformations to afford the desired diarylalkyne products. In general, electrophiles bearing an extended -system lead to products in higher yields than sulfonates with only one aromatic ring.
引用
收藏
页码：1603 / 1610
页数：8
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