Phase diagram of a solution undergoing inverse melting

被引：19

作者：

Angelini, R. ^{[1
]}

Ruocco, G. ^{[1
,2
]}

De Panfilis, S. ^{[1
]}

机构：

[1] Univ Roma La Sapienza, CNR, INFM, Res Ctr SOFT, I-00185 Rome, Italy

[2] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy

来源：

PHYSICAL REVIEW E | 2008年 / 78卷 / 02期

关键词：

D O I：

10.1103/PhysRevE.78.020502

中图分类号：

O35 [流体力学]; O53 [等离子体物理学];

学科分类号：

070204 ; 080103 ; 080704 ;

摘要：

The phase diagram of alpha-cyclodextrin/water/4-methylpyridine solutions, a system undergoing inverse melting, has been studied by differential scanning calorimetry, theological methods, and x-ray diffraction. Two different fluid phases separated by a solid region have been observed in the high a-cyclodextrin concentration range (c >= 150 mg/ml). Decreasing c, the temperature interval where the solid phase exists decreases and eventually disappears, and a first-order phase transition is observed between the two different fluid phases.

引用

页数：4

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