Using nature's blueprint to expand catalysis with Earth-abundant metals

被引：430

作者：

Bullock, R. Morris ^{[1
]}

Chen, Jingguang G. ^{[2
,3
]}

Gagliardi, Laura ^{[4
,5
]}

Chirik, Paul J. ^{[6
]}

Farha, Omar K. ^{[7
]}

Hendon, Christopher H. ^{[8
]}

Jones, Christopher W. ^{[9
]}

Keith, John A. ^{[10
]}

Klosin, Jerzy ^{[11
]}

Minteer, Shelley D. ^{[12
]}

Morris, Robert H. ^{[13
]}

Radosevich, Alexander T. ^{[14
]}

Rauchfuss, Thomas B. ^{[15
]}

Strotman, Neil A. ^{[16
]}

Vojvodic, Aleksandra ^{[17
]}

Ward, Thomas R. ^{[18
]}

Yang, Jenny Y. ^{[19
]}

Surendranath, Yogesh ^{[14
]}

机构：

[1] Pacific Northwest Natl Lab, Ctr Mol Electrocatalysis, Richland, WA 99352 USA

[2] Columbia Univ, Dept Chem Engn, New York, NY 10027 USA

[3] Brookhaven Natl Lab, Chem Div, Upton, NY 11973 USA

[4] Univ Minnesota, Minnesota Supercomp Inst, Dept Chem, Minneapolis, MN 55455 USA

[5] Univ Minnesota, Chem Theory Ctr, Minneapolis, MN 55455 USA

[6] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

[7] Northwestern Univ, Dept Chem & Chem & Biol Engn, Evanston, IL 60208 USA

[8] Univ Oregon, Dept Chem & Biochem, Eugene, OR 97403 USA

[9] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA

[10] Univ Pittsburgh, Dept Chem & Petr Engn, Pittsburgh, PA 15261 USA

[11] Dow Chem Co USA, Core R&D, Midland, MI 48674 USA

[12] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

[13] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[14] MIT, Dept Chem, Cambridge, MA 02139 USA

[15] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA

[16] Merck & Co Inc, Proc Res & Dev, Rahway, NJ 07065 USA

[17] Univ Penn, Dept Chem & Biomol Engn, Philadelphia, PA 19104 USA

[18] Univ Basel, Dept Chem, CH-4058 Basel, Switzerland

[19] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

SCIENCE | 2020年 / 369卷 / 6505期

关键词：

COUPLED ELECTRON-TRANSFER; DENSITY-FUNCTIONAL THEORY; H BOND FUNCTIONALIZATION; ACTIVE-SITE; ORGANIC FRAMEWORK; H-2; EVOLUTION; IRON-SULFUR; REDUCTION; ELECTROCATALYSTS; OXIDATION;

D O I：

10.1126/science.abc3183

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

引用

页码：786 / +

页数：11

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