Melt crystallization of isomeric long-chain aldehydes from hydroformylation

被引：34

作者：

Beierling, Thorsten ^{[1
]}

Osiander, Jan ^{[1
]}

Sadowski, Gabriele ^{[1
]}

机构：

[1] TU Dortmund Univ, Dept Chem & Biochem Engn, Lab Thermodynam, D-44227 Dortmund, Germany

来源：

SEPARATION AND PURIFICATION TECHNOLOGY | 2013年 / 118卷

关键词：

Melt crystallization; Isomers; Sweating; Hydroformylation; Aldehydes; ORGANIC-SOLID SOLUTIONS; LAYER; PURIFICATION; SEPARATION; ALKENES; DESIGN;

D O I：

10.1016/j.seppur.2013.06.023

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

This work evaluates comprehensively the potential of melt crystallization for the separation of the commercially important isomeric long-chain aldehydes. This was investigated with aldehydes of different chain lengths. A broad range of physical parameters was determined and related phase-equilibria were measured and modeled. Achievable growth rates and the corresponding purities were studied in static layer-melt crystallization experiments as function of chain length, cooling rate and concentration. Since aldehydes are highly reactive compounds, two methods were evaluated to guarantee chemical stability during crystallization. Furthermore, the efficiency of sweating was experimentally investigated and mathematically modeled as a function of chain length, temperature, crystal purity and crystalline layer thickness in high accordance to the experimental data. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：13 / 24

页数：12

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