Highly Selective Bis(imino)pyridine Iron-Catalyzed Alkene Hydroboration

被引：175

作者：

Obligacion, Jennifer V. ^{[1
]}

Chirik, Paul J. ^{[1
]}

机构：

[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 11期

基金：

美国国家科学基金会;

关键词：

ASYMMETRIC HYDROBORATION; DEHYDROGENATIVE BORYLATION; RHODIUM; HYDROGENATION; COMPLEXES; HYDROSILYLATION; VINYLARENES; DINITROGEN; MILD;

D O I：

10.1021/ol400990u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis(imino)pyridine iron dinitrogen complexes have been shown to promote the anti-Markovnikov catalytic hydroboration of terminal, Internal, and geminal alkenes with high activity and selectivity. The isolated iron dinitrogen compounds offer distinct advantages in substrate scope and overall performance over known precious metal catalysts and previously reported in situ generated iron species.

引用

页码：2680 / 2683

页数：4

共 50 条

[1] Iron-Catalyzed Alkene Hydroboration with Pinacolborane
Lei, Zhang
Huang, Zheng
SYNLETT, 2013, 24 (14) : 1745 - 1747
[2] Effects of aluminoxane cocatalysts on bis(imino)pyridine iron-catalyzed ethylene oligomerization
Zhang, Wei
Ye, Jian
Jiang, Binbo
Wang, Jingdai
Liao, Zuwei
Huang, Zhengliang
Yang, Yongrong
Ye, Zhibin
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2019, 97 (04): : 903 - 910
[3] Exploring the effects of phenolic compounds on bis(imino)pyridine iron-catalyzed ethylene oligomerization
Ye, Jian
Jiang, Binbo
Qin, Yichao
Zhang, Wei
Chen, Yuming
Wang, Jingdai
Yang, Yongrong
RSC ADVANCES, 2015, 5 (116) : 95981 - 95993
[4] Synthesis and Electronic Structure of Bis(imino)pyridine Iron Metallacyclic Intermediates in Iron-Catalyzed Cyclization Reactions
Hoyt, Jordan M.
Sylvester, Kevin T.
Sernproni, Scott P.
Chirik, Paul J.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (12) : 4862 - 4877
[5] Functional group tolerance and substrate scope in bis(imino)pyridine iron catalyzed alkene hydrogenation
Trovitch, Ryan J.
Lobkovsky, Emil
Bill, Eckhard
Chirik, Paul J.
ORGANOMETALLICS, 2008, 27 (07) : 1470 - 1478
[6] Iron-Catalyzed, Markovnikov-Selective Hydroboration of Styrenes
Chen, Xu
Cheng, Zhaoyang
Lu, Zhan
ORGANIC LETTERS, 2017, 19 (05) : 969 - 971
[7] Bis(imino)pyridine Cobalt-Catalyzed Alkene Isomerization-Hydroboration: A Strategy for Remote Hydrofunctionalization with Terminal Selectivity
Obligacion, Jennifer V.
Chirik, Paul J.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (51) : 19107 - 19110
[8] Iron-Catalyzed Hydroboration of Vinylcyclopropanes
Chen, Chenhui
Shen, Xuzhong
Chen, Jianhui
Hong, Xin
Lu, Zhan
ORGANIC LETTERS, 2017, 19 (19) : 5422 - 5425
[9] Iron-Catalyzed Alkene Hydroalumination
Li, Wen-Tao
Zhang, Qiao
Hu, Meng-Yang
Zhu, Shou-Fei
ORGANIC LETTERS, 2023, 25 (30) : 5646 - 5649
[10] Arene coordination in bis(imino)pyridine iron complexes: Identification of catalyst deactivation pathways in iron-catalyzed hydrogenation and hydrosilation
Archer, Andrew M.
Bouwkamp, Marco W.
Cortez, Maria-Patricia
Lobkovsky, Emil
Chirik, Paul J.
ORGANOMETALLICS, 2006, 25 (18) : 4269 - 4278

← 1 2 3 4 5 →