What can positronium tell us about adsorption?

被引:7
|
作者
Kierys, Agnieszka [1 ]
Zaleski, Radoslaw [2 ]
Tydda, Maciej [2 ]
Goworek, Jacek [1 ]
机构
[1] Marie Curie Sklodowska Univ, Fac Chem, Dept Adsorpt, PL-20031 Lublin, Poland
[2] Marie Curie Sklodowska Univ, Inst Phys, Dept Nucl Methods, PL-20031 Lublin, Poland
关键词
Silica gel; Positron annihilation lifetime spectroscopy (PALS); N-heptane adsorption; ANNIHILATION LIFETIME SPECTROSCOPY; POROUS SILICA; SPECTRA; DESORPTION; PORES; GEL;
D O I
10.1007/s10450-013-9475-x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The condensation and evaporation of n-heptane at 298 K in mesopores of silica material obtained by the polymer templating method have been studied by PALS measurements. It is demonstrated that the ortho-positronium lifetimes and intensities provide valuable information on pore filling and emptying which are not accessible from a conventional adsorption experiment. The results confirm the specific adsorption mechanism of n-heptane in pores with narrow openings (ink-bottle shape) which is different from that known for other pore geometries. The results from PALS experiment are compared to those derived from the conventional n-heptane and nitrogen adsorption data.
引用
收藏
页码:529 / 535
页数:7
相关论文
共 50 条
  • [1] What can positronium tell us about adsorption?
    Agnieszka Kierys
    Radosław Zaleski
    Maciej Tydda
    Jacek Goworek
    Adsorption, 2013, 19 : 529 - 535
  • [2] What can cutans tell us about?
    T. A. Sokolova
    Eurasian Soil Science, 2008, 41 (1) : 102 - 104
  • [3] What Angles Can Tell Us About What Holes Are Not
    Phillip John Meadows
    Erkenntnis, 2013, 78 : 319 - 331
  • [4] What Angles Can Tell Us About What Holes Are Not
    Meadows, Phillip John
    ERKENNTNIS, 2013, 78 (02) : 319 - 331
  • [5] What Can Proteomics Tell Us about Tuberculosis?
    Flores-Villalva, Susana
    Rogriguez-Hernandez, Elba
    Rubio-Venegas, Yesenia
    Germinal Canto-Alarcon, Jorge
    Milian-Suazo, Feliciano
    JOURNAL OF MICROBIOLOGY AND BIOTECHNOLOGY, 2015, 25 (08) : 1181 - 1194
  • [6] What can metabolites tell us about gliomas?
    Sampetrean, Oltea
    Saya, Hideyuki
    NEURO-ONCOLOGY, 2022, 24 (09) : 1469 - 1470
  • [7] WHAT CAN METEORITES TELL US ABOUT REGOLITHS
    WILKENING, LL
    METEORITICS, 1983, 18 (04): : 421 - 422
  • [8] WHAT CAN HISTORY TELL US ABOUT EPIDEMICS?
    Henderson, John
    Cohn, Samuel
    Fara, Patricia
    Hempel, Sandra
    HISTORY TODAY, 2020, 70 (04) : 8 - 10
  • [9] What Can Proteomics Tell Us About Platelets?
    Burkhart, Julia M.
    Gambaryan, Stepan
    Watson, Stephen P.
    Jurk, Kerstin
    Walter, Ulrich
    Sickmann, Albert
    Heemskerk, Johan W. M.
    Zahedi, Rene P.
    CIRCULATION RESEARCH, 2014, 114 (07) : 1204 - 1219
  • [10] What Can the Electroencephalogram Tell Us About Sedation?
    Lynch, Lisa R.
    Saraiya, Neeta
    Chao, Jerry
    Yuan, Ian
    JOURNAL OF NEUROSURGICAL ANESTHESIOLOGY, 2025, 37 (01) : 128 - 132