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What can positronium tell us about adsorption?
被引:7
|作者:
Kierys, Agnieszka
[1
]
Zaleski, Radoslaw
[2
]
Tydda, Maciej
[2
]
Goworek, Jacek
[1
]
机构:
[1] Marie Curie Sklodowska Univ, Fac Chem, Dept Adsorpt, PL-20031 Lublin, Poland
[2] Marie Curie Sklodowska Univ, Inst Phys, Dept Nucl Methods, PL-20031 Lublin, Poland
来源:
关键词:
Silica gel;
Positron annihilation lifetime spectroscopy (PALS);
N-heptane adsorption;
ANNIHILATION LIFETIME SPECTROSCOPY;
POROUS SILICA;
SPECTRA;
DESORPTION;
PORES;
GEL;
D O I:
10.1007/s10450-013-9475-x
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The condensation and evaporation of n-heptane at 298 K in mesopores of silica material obtained by the polymer templating method have been studied by PALS measurements. It is demonstrated that the ortho-positronium lifetimes and intensities provide valuable information on pore filling and emptying which are not accessible from a conventional adsorption experiment. The results confirm the specific adsorption mechanism of n-heptane in pores with narrow openings (ink-bottle shape) which is different from that known for other pore geometries. The results from PALS experiment are compared to those derived from the conventional n-heptane and nitrogen adsorption data.
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页码:529 / 535
页数:7
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