B-O-B Catalyzed Cycloadditions of Acrylic Acids

被引：8
作者：
Zhang, Peng [1 ]
Kriegel, Robert M. [2 ]
Frost, John W. [1 ]
机构：
[1] Michigan State Univ, Dept Chem, 578 South Shaw Lane, E Lansing, MI 48824 USA
[2] Coca Cola Co, 1 Coca Cola Plaza NW, Atlanta, GA 30313 USA
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2016年 / 4卷 / 12期
关键词：
Tetraacetyl diborate; Diphenylborinic anhydride; Acrylic acid; Cycloaddition; Polymerization; DIELS-ALDER REACTION; CARBOXYLIC-ACIDS; TEREPHTHALIC ACID; ACTIVATION;
D O I：
10.1021/acssuschemeng.6b01908
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Lewis-acid-catalyzed cycloadditions of unesterified acrylic acids performed under solvent-free reaction conditions can be environmentally advantageous and afford increased product yields. However, there is also the potential for competing Lewis-acid-catalyzed polymerization reactions and the attendant fire/explosion risks associated with runaway polymerizations. BOB(OAc)(4) (tetraacetyl diborate) and BOBPh4 (diphenylborinic anhydride), which are distinguished by an oxygen bonded to two boron atoms (B-O-B), catalyze high-yielding cycloadditions of unesterified acrylic acids under solvent-free reaction conditions without competing olefin polymerization.
引用
收藏
页码：6991 / 6995
页数：5
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