trans-Carbonyl[η2-dihydrobis(pyrazol-1-yl-N2)borato] hydridobis(triphenylarsine)-ruthenium(II) monohydrate

被引:7
作者
Huh, S [1 ]
Kim, Y [1 ]
Park, S [1 ]
Park, TJ [1 ]
Jun, MJ [1 ]
机构
[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
关键词
D O I
10.1107/S0108270199002279
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The molecule of the title compound, [RuH(C6H8BN4)-(C18H15As)(2)(CO)]. H2O, is a discrete monomeric complex which has the hydride, carbonyl and dihydrobis(pyrazol-1-yl)borate ligands in equatorial positions, and two trans-positioned AsPh3 ligands. The geometry around the Ru-II atom is distorted octahedral. In addition to the water dimer formed by strong intermolecular hydrogen bonds, two possible weak intramolecular hydrogen bonds have been observed within the complex.
引用
收藏
页码:850 / 852
页数:3
相关论文
共 11 条
  • [11] TROFIMENKO S, 1970, INORG SYNTH, V12, P100