trans-Carbonyl[η2-dihydrobis(pyrazol-1-yl-N2)borato] hydridobis(triphenylarsine)-ruthenium(II) monohydrate

被引：7
作者：
Huh, S [1 ]
Kim, Y [1 ]
Park, S [1 ]
Park, TJ [1 ]
Jun, MJ [1 ]
机构：
[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷
关键词：
D O I：
10.1107/S0108270199002279
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The molecule of the title compound, [RuH(C6H8BN4)-(C18H15As)(2)(CO)]. H2O, is a discrete monomeric complex which has the hydride, carbonyl and dihydrobis(pyrazol-1-yl)borate ligands in equatorial positions, and two trans-positioned AsPh3 ligands. The geometry around the Ru-II atom is distorted octahedral. In addition to the water dimer formed by strong intermolecular hydrogen bonds, two possible weak intramolecular hydrogen bonds have been observed within the complex.
引用
收藏
页码：850 / 852
页数：3
相关论文
共 11 条
  • [1] BIS(BENZOTRIAZOL-1-YL)BORATO COMPLEXES OF RUTHENIUM AND RHODIUM
    CARTWRIGHT, J
    HARMAN, A
    HILL, AF
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 396 (2-3) : C31 - C34
  • [2] *ENR NON, 1992, CAD 4 PC SOFTW VERS
  • [3] Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565
  • [4] HARMS K, 1997, XCAD 4 PROGR RED CAD
  • [5] HUH S, 1999, UNPUB INORG CHIM ACT
  • [6] ODULOTA JA, 1979, J AM CHEM SOC, V101, P4787
  • [7] SANCHEZDELGADO RA, 1990, T MET CHEM, V16, P241
  • [8] Sheldrick G.M., 1993, PROGRAM CRYSTAL STRU
  • [9] SHELDRICK GM, 1997, XHELXS 9M PROGRAM SO
  • [10] RECENT ADVANCES IN POLY(PYRAZOLYL)BORATE (SCORPIONATE) CHEMISTRY
    TROFIMENKO, S
    [J]. CHEMICAL REVIEWS, 1993, 93 (03) : 943 - 980
12