Spectroscopic properties of Dy3+-doped NaBi(WO4)2 crystal

被引:25
作者
Jiang, Tianhui [1 ,2 ]
Gong, Xinghong [1 ]
Chen, Yujin [1 ]
Lin, Yanfu [1 ]
Huang, Jianhua [1 ]
Luo, Zundu [1 ]
Huang, Yidong [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
Spectroscopic property; Dy3+:NaBi(WO4)(2) crystal; OPTICAL-PROPERTIES; STIMULATED-EMISSION; SINGLE-CRYSTALS; DY3+; INTENSITIES; ABSORPTION; SPECTRA; GENERATION; LIGHT; IONS;
D O I
10.1016/j.jlumin.2019.02.021
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A Dy3+-doped NaBi(WO4)(2) crystal was successfully grown by the Czochralski method. Spectroscopic properties of the crystal at room temperature were measured and analyzed. Peak absorption cross-sections of the H-6(15/2) -> I-4(15/2) transition for the crystal are 1.4 x 10(-21) and 2.3 x 10(-21) cm(2) with full widths at half maximum of 7.5 and 6.6 nm for sigma and pi polarizations, respectively, and at 454 nm for both polarizations. Meanwhile, the crystal exhibits a strong yellow emission at 574 nm corresponding to the F-4(9/2) -> H-6(13/2) transition with peak cross-sections of 0.97 x 10(-20) and 1.27 x 10(-20) cm(2) for sigma and pi polarizations, respectively. The fluorescence lifetime and quantum efficiency of the F-4(9/2) multiplet were estimated to be 179 mu s and 80%, respectively. It has been found that the cross relaxation plays an important role in the relaxation of the F-4(9/2) multiplet. The results show that the Dy3+:NaBi(WO4)(2) crystal may be a promising gain medium of the 574 nm yellow laser pumped by a blue laser diode at 454 nm.
引用
收藏
页码:83 / 88
页数:6
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