Non-equilibrium conductance through a benzene molecule in the Kondo regime

Starting from exact eigenstates for a symmetric ring, we derive a low-energy effective generalized Anderson Hamiltonian which contains two spin doublets with opposite momenta and a singlet for the neutral molecule. For benzene, the singlet (doublets) represent the ground state of the neutral (singly charged) molecule. We calculate the non-equilibrium conductance through a benzene molecule, doped with one electron or a hole (i.e. in the Kondo regime), and connected to two conducting leads at different positions. We solve the problem using the Keldysh formalism and the non-crossing approximation. When the leads are connected in the para position (at 180 degrees), the model is equivalent to the ordinary impurity Anderson model and its known properties are recovered. For other positions, there is a partial destructive interference in the co-tunneling processes involving the two doublets and, as a consequence, the Kondo temperature and the height and width of the central peak (for bias voltage V-b near zero) of the differential conductance G = dI/dV(b) (where I is the current) are reduced. In addition, two peaks at finite V-b appear. We study the position of these peaks, the temperature dependence of G and the spectral densities. Our formalism can also be applied to carbon nanotube quantum dots with intervalley mixing.