Spectroscopic investigation of the novel charge-transfer complex [(phen)(TCNE)12] formed in the reaction of phenacetin with tetracyanoethylene

被引：13

作者：

AlQaradawi, SY ^{[1
]}

Nour, EM ^{[1
]}

机构：

[1] Univ Qatar, Coll Arts & Sci, Dept Chem & Earth Sci, Doha 2713, Qatar

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2005年 / 62卷 / 1-3期

关键词：

phenacetin; tetracyanoethylene; CT-complex; electronic; infrared; thermal; cyclic voltametry;

D O I：

10.1016/j.saa.2005.01.025

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The charge-transfer (CT) interaction of the electron donor phenacetin (phen) and the pi-electron acceptor tetracyanoethylene (TCNE) has been studied in CH2Cl2. The results obtained indicate the formation of the novel CT-complex with the general formula [(phen)(TCNE)(12)]. The 1:12 stoichiometry of the reaction was based on photometric titration, elemental analysis, infrared, thermal and cyclic voltametry measurements of the formed CT-complex. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：578 / 581

页数：4

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