Novel synthesis of conductive poly(arylene disulfide)/graphite nanocomposite

被引:35
作者
Du, XS
Xiao, M
Meng, YZ
Hay, AS
机构
[1] Zhongshan Univ, Inst Energy & Environm Mat, Sch Phys & Engn, Guangzhou 510275, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
[3] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
graphite oxide; nanocomposite; X-ray diffraction; transmission electron microscopy;
D O I
10.1016/j.synthmet.2003.10.023
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A new process for the synthesis of poly(arylene disulfide)/graphite nanocomposites was developed via in situ polymerization of aromatic dithiols in the presence of exfoliated graphite oxide. The nanoscale dispersion of carbon layer within the matrix was confirmed by X-ray diffraction patterns and TEM examination. The conductivity of the poly(arylene disulfide)/graphite nanocomposite was determined to be increased by about seven orders of magnitude compared with GO. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:129 / 132
页数:4
相关论文
共 36 条
[1]   Effect of co-intercalated organic solvents in graphite on electrochemical Li intercalation [J].
Abe, T ;
Mizutani, Y ;
Kawabata, N ;
Inaba, M ;
Ogumi, Z .
SYNTHETIC METALS, 2001, 125 (02) :249-253
[2]  
BOTTINO F, 1979, TETRAHEDRON LETT, P1171
[3]   Selective liquid sorption properties of hydrophobized graphite oxide nanostructures [J].
Dékány I. ;
Krüger-Grasser R. ;
Weiss A. .
Colloid and Polymer Science, 1998, 276 (7) :570-576
[4]   THE USE OF POLYDISULFIDES AND COPOLYMERIC DISULFIDES IN THE LI/PEO/SRPE BATTERY SYSTEM [J].
DOEFF, MM ;
LERNER, MM ;
VISCO, SJ ;
DEJONGHE, LC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (08) :2077-2081
[5]  
FEHER F, 1967, ANGEW CHEM INT EDIT, V6, P703, DOI 10.1002/anie.196707031
[6]  
Fujiwara S., 1976, Japanese patent application, Patent No. 109998
[7]   Transition metals oxyfluorides intercalated into graphite: new synthesis route and electrochemical properties [J].
Giraudet, J ;
Claves, D ;
Hamwi, A .
SYNTHETIC METALS, 2001, 118 (1-3) :57-63
[8]   Some chemical and electrochemical properties of graphite oxide [J].
Hamwi, A ;
Marchand, V .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1996, 57 (6-8) :867-872
[9]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[10]   Structure of graphite oxide revisited [J].
Lerf, A ;
He, HY ;
Forster, M ;
Klinowski, J .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (23) :4477-4482