Rare earth thiocyanate complexes with 18-crown-6 co-ligands

被引：8

作者：

Bakker, Jacinta M. ^{[1
]}

Deacon, Glen B. ^{[1
]}

Junk, Peter C. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

POLYHEDRON | 2013年 / 52卷

关键词：

Lanthanoids; Rare earths; Thiocyanates; Crown ethers; CROWN-ETHER COMPLEXES; CRYSTAL-STRUCTURE; LANTHANIDE(III) COMPLEXES; IONIC-RADII; SERIES;

D O I：

10.1016/j.poly.2012.08.028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [Ln(NCS)(3)(THF)(4)](2) or [Yb(NCS)(3)(THF)(4)] with 18-crown-6 yields the moisture-stable [Ln(NCS)(3)(18-crown-6)] (Ln = La, Nd, Dy, Yb) complexes. Although the Ln contraction does not affect the coordination number, the crown ether is decreasingly folded with decreasing ion size. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：560 / 564

页数：5

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