Special Features of Oxide Layer Formation on Magnesium Alloys during Plasma Electrolytic Oxidation

被引:1
作者
Kossenko, A. [1 ]
Zinigrad, M. [1 ]
机构
[1] Ariel Univ, Sci Pk, IL-40700 Ariel, Israel
关键词
plasma electrolytic oxidation; surface treatment; magnesium; islands mechanism; anomalous voltage form; MICRO-ARC OXIDATION; CORROSION BEHAVIOR; MG ALLOY; CONTAINING COATINGS; ALUMINUM-ALLOYS; HIGH EMISSIVITY; PEO COATINGS; DUTY CYCLE; AZ31; RESISTANCE;
D O I
10.1134/S1087659618020098
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The process of the oxidation of magnesium alloys in a silicate electrolyte during plasma electrolytic oxidation is investigated. An anomalous form of the chronogram of the formation voltage of the oxide layer in the electrolytes with the highest silicate concentration (approximately 0.15 M Na2SiO3 center dot 5H(2)O) is detected. X-ray diffraction analysis, scanning electron microscopy with energy dispersive X-ray spectroscopy analysis, and thickness gauges are used to characterize the surface microstructure, phase composition, and thickness, respectively. Mechanisms for the initial period of PEO and the "insular" growth were described. During the "insular" growth, islands consisting of vitrified components of the electrolyte are growing on the original smooth surface.
引用
收藏
页码:62 / 70
页数:9
相关论文
共 55 条
[31]   Production of ceramic layers on aluminum alloys by plasma electrolytic oxidation in alkaline silicate electrolytes [J].
Lugovskoy, Alex ;
Zinigrad, Michael ;
Kossenko, Aleksey ;
Kazanski, Barbara .
APPLIED SURFACE SCIENCE, 2013, 264 :743-747
[32]   Plasma electrolytic oxide layers as promising systems for catalysis [J].
Lukiyanchuk, I. V. ;
Rudnev, V. S. ;
Tyrina, L. M. .
SURFACE & COATINGS TECHNOLOGY, 2016, 307 :1183-1193
[33]   Systematic study of the electrolytic plasma oxidation process on a Mg alloy for corrosion protection [J].
Ma, Y ;
Nie, X ;
Northwood, DO ;
Hu, H .
THIN SOLID FILMS, 2006, 494 (1-2) :296-301
[34]   Silicate-based Plasma Electrolytic Oxidation (PEO) coatings with incorporated CeO2 particles on AM50 magnesium alloy [J].
Mohedano, M. ;
Blawert, C. ;
Zheludkevich, M. L. .
MATERIALS & DESIGN, 2015, 86 :735-744
[35]   Mechanisms of creep deformation in Mg-Sc-based alloys [J].
Mordike, BL ;
Stulíková, I ;
Smola, B .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2005, 36A (07) :1729-1736
[36]   Effect of fluoride on plasma electrolytic oxidation of AZ61 magnesium alloy [J].
Nemcova, A. ;
Skeldon, P. ;
Thompson, G. E. ;
Pacal, B. .
SURFACE & COATINGS TECHNOLOGY, 2013, 232 :827-838
[37]   Microstructure refinement and its effect on specific strength and bio-corrosion resistance in ultralight Mg-4Li-1Ca (LC41) alloy by hot rolling [J].
Nene, S. S. ;
Kashyap, B. P. ;
Prabhu, N. ;
Estrin, Y. ;
Al-Samman, T. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 615 :501-506
[38]   Effect of cathodic micro-discharges on oxide growth during plasma electrolytic oxidation (PEO) [J].
Nomine, A. ;
Martin, J. ;
Henrion, G. ;
Belmonte, T. .
SURFACE & COATINGS TECHNOLOGY, 2015, 269 :131-137
[39]   The evidence of cathodic micro-discharges during plasma electrolytic oxidation of light metallic alloys and micro-discharge intensity depending on pH of the electrolyte [J].
Rakoch, A. G. ;
Gladkova, A. A. ;
Linn, Zayar ;
Strekalina, D. M. .
SURFACE & COATINGS TECHNOLOGY, 2015, 269 :138-144
[40]   In Vitro Analysis of Electrophoretic Deposited Fluoridated Hydroxyapatite Coating on Micro-arc Oxidized AZ91 Magnesium Alloy for Biomaterials Applications [J].
Razavi, Mehdi ;
Fathi, Mohammadhossein ;
Savabi, Omid ;
Vashaee, Daryoosh ;
Tayebi, Lobat .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2015, 46A (03) :1394-1404