Effects of the ratio of anodic and cathodic currents on the characteristics of micro-arc oxidation ceramic coatings on Al alloys

被引:110
作者
Wang, Jun-Hua [1 ,2 ,3 ]
Du, Mao-Hua [1 ]
Han, Fu-Zhu [2 ,3 ]
Yang, Jing [4 ]
机构
[1] Kunming Univ Sci & Technol, Fac Mech & Elect Engn, Kunming 650500, Peoples R China
[2] Tsinghua Univ, Dept Mech Engn, Beijing 100084, Peoples R China
[3] Beijing Key Lab Precis Ultraprecis Mfg Equipments, Beijing 100084, Peoples R China
[4] Beijing Univ Posts & Telecommun, Beijing 100876, Peoples R China
关键词
Micro-arc oxidation; Al alloys; Cathodic current; Anodic current; Ceramic coatings; PLASMA ELECTROLYTIC OXIDATION; ALUMINUM-ALLOY; PHASE-COMPOSITION; MORPHOLOGY; BEHAVIOR;
D O I
10.1016/j.apsusc.2013.12.028
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The micro-arc oxidation (MAO) has increasingly gained attention as a novel and unique technique for depositing thick, dense, and ultra-hard ceramic coatings on aluminum and its alloys substrates. For the MAO technology, discharge parameter, especially the cathodic current, has an important effect on the characteristics of ceramic coatings. But the effects of the ratio of anodic and cathodic currents on properties of the ceramic coatings on Al alloys are rarely studied. This work investigates the effects of the ratio of anodic and cathodic currents under the constant current density on morphology, phase composition, microstructure, and properties of ceramic coatings on 6061 Al alloys. It is found that the ceramic coatings surface roughness Ra is decreasing, and the hardness of ceramic coatings is increasing with the decrease of the ratio. The ceramic coatings are mainly composed of a large amount of alpha-Al2O3 and gamma-Al2O3. The content of alpha-Al2O3 in the ceramic coatings increases with the decrease of the ratio. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:658 / 664
页数:7
相关论文
共 15 条
[1]  
Callister W.D., 1997, MAT SCI ENG INTRO
[2]   Composition and adhesion of protective coatings on aluminum [J].
Gnedenkov, SV ;
Khrisanfova, OA ;
Zavidnaya, AG ;
Sinebrukhov, SL ;
Gordienko, PS ;
Iwatsubo, S ;
Matsui, A .
SURFACE & COATINGS TECHNOLOGY, 2001, 145 (1-3) :146-151
[3]   Growth mechanism and corrosion behavior of ceramic coatings on aluminum produced by autocontrol AC pulse PEO [J].
Guan, YongJun ;
Xia, Yuan ;
Li, Guang .
SURFACE & COATINGS TECHNOLOGY, 2008, 202 (19) :4602-4612
[4]   Surface morphology, composition and thermal behavior of tungsten-containing anodic spark coatings on aluminium alloy [J].
Lukiyanchuk, IV ;
Rudnev, VS ;
Kuryavyi, VG ;
Boguta, DL ;
Bulanova, SB ;
Gordienko, PS .
THIN SOLID FILMS, 2004, 446 (01) :54-60
[5]   An investigation into the mechanical and tribological properties of plasma electrolytic oxidation and hard-anodized coatings on 6082 aluminum alloy [J].
Malayoglu, Ugur ;
Tekin, Kadir C. ;
Malayoglu, Ufuk ;
Shrestha, Suman .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2011, 528 (24) :7451-7460
[6]   AC PEO of aluminium with porous alumina precursor films [J].
Matykina, E. ;
Arrabal, R. ;
Skeldon, P. ;
Thompson, G. E. ;
Belenguer, P. .
SURFACE & COATINGS TECHNOLOGY, 2010, 205 (06) :1668-1678
[7]   Cathodic pulse breakdown of anodic films on aluminium in alkaline silicate electrolyte - Understanding the role of cathodic half-cycle in AC plasma electrolytic oxidation [J].
Sah, Santosh Prasad ;
Tsuji, Etsushi ;
Aoki, Yoshitaka ;
Habazaki, Hiroki .
CORROSION SCIENCE, 2012, 55 :90-96
[8]  
Slonova AI, 2008, PROT MET+, V44, P65, DOI [10.1007/s11124-008-1009-7, 10.1134/S0033173208010098]
[9]   Anodic processes in plasma electrolytic oxidation of aluminium in alkaline solutions [J].
Snizhko, LO ;
Yerokhin, AL ;
Pilkington, A ;
Gurevina, NL ;
Misnyankin, DO ;
Leyland, A ;
Matthews, A .
ELECTROCHIMICA ACTA, 2004, 49 (13) :2085-2095
[10]   Mechanisms underlying the formation of thick alumina coatings through the MAO coating technology [J].
Sundararajan, G ;
Krishna, LR .
SURFACE & COATINGS TECHNOLOGY, 2003, 167 (2-3) :269-277