Synthesis and magnetic properties of novel containing 1,10-phenanthroline polymeric complexes

被引：11
|
作者：
Jiang, HJ
Sun, WL [1 ]
Zheng, RH
机构：
[1] Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China
[2] Taizhou Univ, Dept Biosci & Med Chem, Taizhou 317000, Peoples R China
来源：
EUROPEAN POLYMER JOURNAL | 2006年 / 42卷 / 02期
关键词：
synthesis; polymer containing phenanthroline; polymeric complexes; organic soft ferromagnets;
D O I：
10.1016/j.eurpolymj.2005.07.003
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The polymer (DAPcTPA) was synthesized by polycondensation of 5,6-diamine-1,10-phenanthroline (DAP) with terephthaldehyde (TPA). Three polymeric complexes were first prepared from polymer (DAPcTPA) and NiSO4, COCl2 or FeSO4, respectively. The structures of polymer and complexes were characterized by IR, H-1 NMR spectra and elemental analysis. The magnetic behavior of these complexes was measured as a function of magnetic field strength (050 kOe) at 5 K and as a function of temperature (5-300 K) at a magnetic field strength of 30 kOe. The results show that DAPcTPA-Ni2+ and DAPcTPA-Co2+ are soft ferromagnets, while DAPcTPA-Fe2+ exhibits features of an antiferromagnet. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：425 / 433
页数：9
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