Catalytic pyrolysis of bamboo residue and its extracted three main components over copper modified ZSM-5 for the production of aromatic hydrocarbons

被引:7
|
作者
Wang, Yichen [1 ,2 ,3 ]
Li, Yingkai [1 ,2 ,3 ]
Li, Chong [1 ,2 ,3 ]
Chai, Meiyun [1 ,2 ,3 ]
Yellezuome, Dominic [1 ,2 ,3 ]
Liu, Ronghou [1 ,2 ,3 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Agr & Biol, Biomass Energy Engn Res Ctr, 800 Dongchuan Rd, Shanghai 200240, Peoples R China
[2] Minist Sci & Technol, Shanghai Yangtze River Delta Eco Environm Change, 800 Dongchuan Rd, Shanghai 200240, PR, Peoples R China
[3] Minist Agr & Rural Affairs, Key Lab Urban Agr South, 800 Dongchuan Rd, Shanghai 200240, Peoples R China
关键词
Bamboo residue; Catalytic fast pyrolysis; ZSM-5; MAHs Three main components; KINETICS; BIOMASS; LIGNIN; HEMICELLULOSE; TORREFACTION;
D O I
10.1016/j.jaap.2022.105692
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this study, the product distribution from the catalytic pyrolysis of bamboo residue and its three main extracted components (cellulose, hemicellulose, and lignin) over Copper (Cu) modified ZSM-5 with different loading rates was conducted using pyrolysis-gas chromatography/mass spectroscopy. The addition of Cu modified ZSM-5 reduced the relative content of phenols, while that of monocyclic aromatic hydrocarbons (MAHs) increased significantly. The relative content of MAHs for the bamboo residue without catalyst was 2.10%, which increased considerably by 66.67% over Cu(2)/ZSM-5. The MAHs yield in cellulose is 3.03 times as that of the bamboo residue during catalytic pyrolysis over Cu(2)/ZSM-5. Phenolic compounds are mainly produced by lignin, whereas cellulose and hemicellulose are the primary producers of ketones and aldehydes. This study is crucial for understanding the pyrolytic product distribution of the bamboo residue and its three main extracted components.
引用
收藏
页数:9
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