Ion imprinted polymers for the selective extraction of silver(I) ions in aqueous media: Kinetic modeling and isotherm studies

被引：48

作者：

Ahamed, Meh ^{[1
]}

Mbianda, X. Y. ^{[1
]}

Mulaba-Barubiandi, A. F. ^{[2
]}

Marjanovic, Ljiljana ^{[3
]}

机构：

[1] Univ Johannesburg, Fac Sci, Dept Appl Chem, Johannesburg, South Africa

[2] Univ Johannesburg, Fac Sci, Fac Engn & Built Environm, Mineral Proc & Technol Res Ctr,Dept Met, Johannesburg, South Africa

[3] Univ Johannesburg, Fac Sci, Dept Chem, Johannesburg, South Africa

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2013年 / 73卷 / 03期

关键词：

Ion imprinting polymer; Selective extraction; Kinetic modeling and isotherm; Silver(I) ions; METAL-IONS; CROWN-ETHER; ADSORPTION; RECOVERY; CHITOSAN; REMOVAL; SEPARATION; RECOGNITION; RESINS; WATER;

D O I：

10.1016/j.reactfunctpolym.2012.11.011

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Ion imprinted polymers (IIPs) for selective extraction of Ag(I) ions from aqueous solution were synthesized by a precipitation polymerization method using two functional monomers, 4-vinyl pyridine (4-VP) and 1-vinyl imidazole (1-VID), and N,N-ethylene bisacrylamide (EBArn) as the cross linker. Batch adsorption experiments were carried out as a function of Ag(l) imprinted polymer amount, agitation time, pH and initial Ag(I) concentration. The kinetic studies indicated that pseudo-second-order kinetic model best describes the adsorption behavior, while the adsorption data correlated well with the Langmuir isotherm. Furthermore the selectivity studies revealed that the ion imprinted polymers had a higher absorption capacity and a higher selectivity, for the Ag(I) ions, than the control polymers. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：474 / 483

页数：10

共 24 条

[1] Recovery of silver from industrial wastes, cassava solution effects [J].

Ajiwe, VIE ;

Anyadiegwu, IE .

SEPARATION AND PURIFICATION TECHNOLOGY, 2000, 18 (02) :89-92

[2]

Asem A.A., 2005, HYDROMETALLURGY, V80, P98

[3] Synthesis and characterization of metal ion imprinted nano-porous polymer for the selective recognition of copper [J].

Baghel, Anuradha ;

Boopathi, M. ;

Singh, Beer ;

Pandey, Pratibha ;

Mahato, T. H. ;

Gutch, P. K. ;

Sekhar, K. .

BIOSENSORS & BIOELECTRONICS, 2007, 22 (12) :3326-3334

[4] Synthesis of Cr(VI)-imprinted poly(4-vinyl pyridine-co-hydroxyethyl methacrylate) particles: Its adsorption propensity to Cr(VI) [J].

Bayramoglu, Gulay ;

Arica, M. Yakup .

JOURNAL OF HAZARDOUS MATERIALS, 2011, 187 (1-3) :213-221

[5] Synthesis of a novel dithiooxamide-formaldehyde resin and its application to the adsorption and separation of silver ions [J].

Celik, Zeliyha ;

Guelfen, Mustafa ;

Aydin, Ali Osman .

JOURNAL OF HAZARDOUS MATERIALS, 2010, 174 (1-3) :556-562

[6] Intraparticle diffusion processes during acid dye adsorption onto chitosan [J].

Cheung, W. H. ;

Szeto, Y. S. ;

McKay, G. .

BIORESOURCE TECHNOLOGY, 2007, 98 (15) :2897-2904

[7] A comparison of the properties of natural clinoptilolites and their ion-exchange capacities for silver removal [J].

Coruh, Semra ;

Senel, Gaye ;

Ergun, Osman Nuri .

JOURNAL OF HAZARDOUS MATERIALS, 2010, 180 (1-3) :486-492

[8] Preconcentrative separation of palladium(II) using palladium(II) ion-imprinted polymer particles formed with different quinoline derivatives and evaluation of binding parameters based on adsorption isotherm models [J].

Daniel, S ;

Babu, PEJ ;

Rao, TP .

TALANTA, 2005, 65 (02) :441-452

[9] Recovery of precious metals through biosorption - A review [J].

Das, Nilanjana .

HYDROMETALLURGY, 2010, 103 (1-4) :180-189

[10] Extraction and separation studies of silver(I) and copper(II) from their aqueous solution using chemically modified melamine resins [J].

El-Ghaffar, M. A. Abd ;

Abdel-Wahab, Z. H. ;

Elwakeel, K. Z. .

HYDROMETALLURGY, 2009, 96 (1-2) :27-34

← 1 2 3 →