Amperometric sensor based on carbon nanotubes and electropolymerized vanillic acid for simultaneous determination of ascorbic acid, dopamine, and uric acid

被引:36
作者
da Silva, L. V. [1 ,2 ,5 ]
Silva, F. A. S. [4 ,5 ]
Kubota, L. T. [4 ,5 ]
Lopes, C. B. [3 ]
Lima, P. R. [3 ,5 ]
Costa, E. O. [1 ,5 ]
Pinho Junior, W. [1 ,5 ]
Goulart, M. O. F. [1 ,5 ]
机构
[1] Univ Fed Alagoas, Inst Quim & Biotecnol, Campus AC Simoes,Ave Lourival Melo Mota S-N, BR-57072970 Maceio, AL, Brazil
[2] Inst Fed Educ Ciencia & Tecnol Alagoas, IFAL, Campus Palmeira dos Indios, BR-57608180 Palmeira Dos Indios, AL, Brazil
[3] Inst Fed Educ Ciencia & Tecnol Alagoas, IFAL, BR-57020600 Maceio, AL, Brazil
[4] Inst Fed Educ Ciencia & Tecnol Goias, IFG, Campus Uruacu, BR-76400000 Uruacu, Go, Brazil
[5] Univ Estadual Campinas, Inst Nacl Ciencia & Tecnol Bioanalit, C Postal 6154, BR-13084971 Campinas, SP, Brazil
关键词
Vanillic acid; Electroanalysis; Ascorbic acid; Dopamine; Uric acid; Chemically modified electrodes; Quinone/hydroquinone system; SIMULTANEOUS ELECTROCHEMICAL DETERMINATION; ELECTRODE; PASTE;
D O I
10.1007/s10008-016-3129-3
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This paper describes the development of a simple and efficient nanostructured platform based on multi-walled carbon nanotubes (MWCNT) functionalized with an in situ generated vanillic acid (VA) polymer. It was used as an analytical sensor for the simultaneous determination of ascorbic acid (AA), dopamine (DA), and uric acid (UA). The electropolymerization process of VA, performed on MWCNT-modified glassy carbon electrode, produces three redox systems based on quinone/hydroquinone functionality, as observed by cyclic voltammetry. The amperometric sensor has as figures of merit for the simultaneous determination of AA, DA, and UA the following values: for AA, a linear range of 5-120 mu M and detection limit of 3.5 mu M; for DA, a linear range of 5-120 mu M and detection limit of 4.5 mu M; and for UA, a linear range of 5-120 mu M and a detection limit of 1.5 mu M. From the obtained performance, the development of the platform based on MWCNT/poly-VA is justified for the simultaneous determination of AA, DA, and UA.
引用
收藏
页码:2389 / 2393
页数:5
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