Catalysis in glycerol: a survey of recent advances

被引：19

作者：

Tagliapietra, Silvia ^{[1
,2
]}

Orio, Laura ^{[1
,2
]}

Palmisano, Giovanni ^{[3
]}

Penoni, Andrea ^{[3
]}

Cravotto, Giancarlo ^{[1
,2
]}

机构：

[1] Univ Turin, Dipartimento Sci & Tecnol Farmaco, I-10125 Turin, Italy

[2] Univ Turin, NIS Ctr Nanostruct Interfaces & Surfaces, I-10125 Turin, Italy

[3] Univ Insubria, Dipartimento Sci & Alta Tecnol, I-22100 Como, Italy

来源：

CHEMICAL PAPERS | 2015年 / 69卷 / 12期

关键词：

glycerol and derivatives; green" solvent; catalysis; transition-metals complexes; catalyst recycling; PALLADIUM NANOPARTICLES; TRANSFER-HYDROGENATIONS; GREEN SOLVENT; REDUCTION; KETONES;

D O I：

10.1515/chempap-2015-0166

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

There is currently a significant increase in the use of glycerol as a renewable solvent for catalytic reactions. Glycerol has often been the solvent of choice in both homogeneous and heterogeneous catalyses, despite its high viscosity at ambient temperature and the low solubility of highly hydrophobic reagents found in glycerol. Its biodegradability and non-toxicity have led to reports of improved reaction performance and selectivity, as well as easier product separation and effective catalyst recycling. All relevant advances in this emerging field of "green" catalysis are thoroughly reviewed below. (C) 2015 Institute of Chemistry, Slovak Academy of Sciences

引用

页码：1519 / 1531

页数：13

共 38 条

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