PCC-Promoted Dehydration of Aldoximes: A Convenient Access to Aromatic, Heteroaromatic, and Aliphatic Nitriles

被引：4

作者：

Chandrappa, S. ^{[1
]}

Prasanna, T. S. R. ^{[2
]}

Vinaya, K. ^{[1
]}

Prasanna, D. S. ^{[1
]}

Rangappa, K. S. ^{[1
]}

机构：

[1] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India

[2] Sri Krisnadevaraya Univ, Dept Polymer Sci & Technol, Synthet Polymer Lab, Anantapur, Andhra Pradesh, India

来源：

SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 20期

关键词：

Aldoxime; carbonyl group; dehydration; nitrile; oxidizing agent; PCC; EFFICIENT BECKMANN REARRANGEMENT; CATALYST; OXIMES; CONVERSION; AMIDES; SYSTEM;

D O I：

10.1080/00397911.2012.738459

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and convenient procedure for the synthesis of nitriles by dehydration of aldoximes using a PCC (pyridiniumchlorochromate) has been developed. A variety of aromatic, heteroaromatic, and aliphatic aldoximes are converted. Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the full spectral details.

引用

页码：2756 / 2762

页数：7

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