Synthesis and Crystal Structure of tris-(1,10-Phenanthroline)-Iron(II) Dichromate Tetrahydrate, Fe(C12H8N2)3Cr2O7•4H2O

被引：0

作者：

Liu, Hai-Xing ^{[1
]}

Jian, Fang-Fang ^{[2
]}

Wang, Jing ^{[2
]}

Yu, Zhang-Xue ^{[1
]}

Zhang, Qing-Hua ^{[1
]}

Tai, Xi-Shi ^{[1
]}

机构：

[1] Weifang Univ, Coll Chem & Chem Engn, Weifang 261061, Peoples R China

[2] Qingdao Univ Sci & Technol, New Mat & Funct Coordinat Chem Lab, Qingdao 266042, Peoples R China

来源：

ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 06期

基金：

美国国家科学基金会;

关键词：

Crystal structure; Fe(C12H8N2)(3)CR2O7 center dot 4H(2)O; COMPLEXES; 1,10-PHENANTHROLINE; LIGAND;

D O I：

10.14233/ajchem.2013.13747

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this report, Fe(C12H8N2)(3)Cr2O7 center dot 4H(2)O, was prepared by the reactor of FeCl2, 1,10-phenanthroline and potassium chromate. The asymmetric unit is composed of a [Fe(phen)(3)](2+) cation, a Cr2O72- anion and four water molecules. The metal centre is coordinated in a distorted octahedral mode by six N atoms from three 1,10-phenanthroline. The Cr2O72- anion is in a staggered conformation. The crystal packing is stabilized by intermolecular O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds and pi-pi interaction.

引用

页码：3515 / 3516

页数：2

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