Synthesis and Crystal Structure of tris-(1,10-Phenanthroline)-Iron(II) Dichromate Tetrahydrate, Fe(C12H8N2)3Cr2O7•4H2O

被引：0
|
作者：
Liu, Hai-Xing [1 ]
Jian, Fang-Fang [2 ]
Wang, Jing [2 ]
Yu, Zhang-Xue [1 ]
Zhang, Qing-Hua [1 ]
Tai, Xi-Shi [1 ]
机构：
[1] Weifang Univ, Coll Chem & Chem Engn, Weifang 261061, Peoples R China
[2] Qingdao Univ Sci & Technol, New Mat & Funct Coordinat Chem Lab, Qingdao 266042, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 06期
基金：
美国国家科学基金会;
关键词：
Crystal structure; Fe(C12H8N2)(3)CR2O7 center dot 4H(2)O; COMPLEXES; 1,10-PHENANTHROLINE; LIGAND;
D O I：
10.14233/ajchem.2013.13747
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this report, Fe(C12H8N2)(3)Cr2O7 center dot 4H(2)O, was prepared by the reactor of FeCl2, 1,10-phenanthroline and potassium chromate. The asymmetric unit is composed of a [Fe(phen)(3)](2+) cation, a Cr2O72- anion and four water molecules. The metal centre is coordinated in a distorted octahedral mode by six N atoms from three 1,10-phenanthroline. The Cr2O72- anion is in a staggered conformation. The crystal packing is stabilized by intermolecular O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds and pi-pi interaction.
引用
收藏
页码：3515 / 3516
页数：2
相关论文
共 50 条
  • [31] Crystal structure of diaqua(1,10-phenanthroline)nickel(II) methanedisulfonate, Ni(H2O)2(C12H8N2)[CH2(SO3)2]
    Kan, Wei-Qiu
    Liu, Ying-Ying
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2010, 225 (02): : 329 - 330
  • [32] Crystal structure of [N-(2-aminoethyl)iminodiacetato](1,10-phenanthroline)copper(II) tetrahydrate, [Cu(Aeida)(Phen)] · 4H2O
    A. L. Poznyak
    A. S. Antsyshkina
    G. G. Sadikov
    V. S. Sergienko
    L. V. Stopolyanskaya
    Crystallography Reports, 2005, 50 : 606 - 609
  • [33] Crystal structure of [N-(2-aminoethyl)iminodiacetato](1,10-phenanthroline)copper(II) tetrahydrate, [Cu(Aeida)(Phen)] • 4H2O
    Poznyak, AL
    Antsyshkina, AS
    Sadikov, GG
    Sergienko, VS
    Stopolyanskaya, LV
    CRYSTALLOGRAPHY REPORTS, 2005, 50 (04) : 606 - 609
  • [34] Crystal structure of tetrakis(1,10-phenanthroline)-tetrakis(2-hydroxy-3,5-dinitrobenzoato)tetrazinc(II), Zn4(C12H8N2)4(C7H2N2O7)4
    Liu, Yin-Qiu
    Zhang, Ding-Wa
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (02): : 259 - 263
  • [35] Crystal structure of triaqua(1,10-phenanthroline-N,N′)sulfatonickel(II) hydrate, Ni(H2O)3(C12H8N2)(SO4)•H2O
    Zheng, YQ
    Kong, ZP
    Lin, JL
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2002, 217 (02): : 197 - 198
  • [36] Crystal structure of bis[di(1,10-phenanthroline)azidocopper(II)] biphenyl-4,4′-dicarboxylate pentahydrate, [Cu(C12H8N2)2N3]2(C14H8O4) •5H2O
    Ye, MD
    Cheng, YQ
    Li, XH
    Hu, ML
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2004, 219 (02): : 165 - 167
  • [37] Crystal structure of (1,10-phenanthroline-N,N′)-bis(2-fluorobenzoato)cadmium(II), Cd(C7H4O2F)2(C12H8N2)
    Lou, Qi-Zheng
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2007, 222 (02): : 105 - 106
  • [38] Crystal structure of triaqua(1,10-phenanthroline-N,N′)sulfatonickel(II), Ni(H2O)3(C12H8N2)SO4
    He, HY
    Zhou, YL
    Zhu, LG
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2003, 218 (04): : 563 - 564
  • [39] Crystal structure of chloro(glycinato-N,O)(1,10-phenanthroline-N,N′)-copper(II) trihydrate, [CuCl(C2H4NO2)(C12H8N2)]•3H2O
    Zheng, YQ
    Kong, ZP
    Lin, JL
    Zhou, LX
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2001, 216 (01): : 137 - 138
  • [40] Crystal structure of aqua-methylacrylato-bis(1,10-phenanthroline)-manganese(II) perchlorate monohydrate, [Mn(H2O)(C4H5O2)(C12H8N2)2][CIO4] • H2O
    Cai, Tie-Jun
    Jiang, Wen-Jun
    Deng, Qian
    Peng, Zhen-Shan
    Long, Yun-Fei
    Liu, Chang-E
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2007, 222 (01): : 33 - 35
12345