Silver-catalysed trifluoromethylation of arenes at room temperature

被引：105

作者：

Seo, Sangwon ^{[1
]}

Taylor, John B. ^{[2
]}

Greaney, Michael F. ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[2] Syngenta, Jealotts Hill Int Res Ctr, Bracknell RG42 6EY, Berks, England

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 57期

基金：

英国工程与自然科学研究理事会;

关键词：

PD(II)-CATALYZED ORTHO-TRIFLUOROMETHYLATION; OXIDATIVE TRIFLUOROMETHYLATION; MEDIATED TRIFLUOROMETHYLATION; PHOTOCHEMICAL TRIFLUOROMETHYLATION; HETEROAROMATIC-COMPOUNDS; BENZOIC-ACIDS; ARYL IODIDES; TRIFLUOROMETHANESULFINATE; PERFLUOROALKYLATION; FLUORINATION;

D O I：

10.1039/c3cc41829d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A variety of heteroarenes and electron rich arenes can be trifluoromethylated at room temperature with TMSCF3, catalytic silver and PhI(OAc)(2).

引用

页码：6385 / 6387

页数：3

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