Organic Salts and Merrifield Resin Supported [PM12O40]3- (M = Mo or W) as Catalysts for Adipic Acid Synthesis

被引：23

作者：

Pisk, Jana ^{[1
,2
]}

Agustin, Dominique ^{[1
,2
]}

Poli, Rinaldo ^{[1
,3
]}

机构：

[1] Univ Toulouse, CNRS, LCC, UPS,INPT, 205 Route Narbonne, F-31077 Toulouse, France

[2] Univ Toulouse, IUT P Sabatier, Dept Chim, Ave G Pompidou,BP 20258, F-81104 Castres, France

[3] Inst Univ France, 103 Bd St Michel, F-75005 Paris, France

来源：

MOLECULES | 2019年 / 24卷 / 04期

关键词：

polyoxometalates; Merrifield resin; cyclohexene; adipic acid; organic solvent-free process; OXIDATIVE CLEAVAGE; HYDROGEN-PEROXIDE; SELECTIVE OXIDATION; PHASE OXIDATION; CLEAN SYNTHESIS; SOLVENT-FREE; CYCLOHEXENE; POLYOXOMETALATE; COMPLEXES; H2O2;

D O I：

10.3390/molecules24040783

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Adipic acid (AA) was obtained by catalyzed oxidation of cyclohexene, epoxycyclohexane, or cyclohexanediol under organic solvent-free conditions using aqueous hydrogen peroxide (30%) as an oxidizing agent and molybdenum- or tungsten-based Keggin polyoxometalates (POMs) surrounded by organic cations or ionically supported on functionalized Merrifield resins. Operating under these environmentally friendly, greener conditions and with low catalyst loading (0.025% for the molecular salts and 0.001-0.007% for the supported POMs), AA could be produced in interesting yields.

引用

页数：15

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