Synthesis of dendritic triphenylamine derivatives for dye-sensitized solar cells

被引：43
作者：
Jia, Junhui [1 ]
Zhang, Yuan [2 ]
Xue, Pengchong [1 ]
Zhang, Peng [1 ]
Zhao, Xin [1 ]
Liu, Baijun [1 ]
Lu, Ran [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
[2] Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China
来源：
DYES AND PIGMENTS | 2013年 / 96卷 / 02期
基金：
中国国家自然科学基金;
关键词：
DSSC; Dendritic triphenylamine; pi-Linker; Furan; Thiophene; Benzene; COUMARIN DYES; ORGANIC-DYES; MOLECULAR DESIGN; EFFICIENCY; PERFORMANCE; DONOR;
D O I：
10.1016/j.dyepig.2012.09.015
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Three new donor-it-acceptor (D-pi-A) metal-free organic dyes, in which dendritic triphenylamine acts as donor, and furan, thiophene and benzene as pi-linkers, were synthesized, characterized and used for the application of dye sensitized solar cell (DSSC). Among the fabricated DSSCs, the device based on the furan as it-linker exhibited a short circuit current density of 14.56 mA cm(-2), an open circuit photo voltage of 0.71 V and a fill factor of 0.59, implying a power conversion efficiency (eta) of 6.10%. The devices sensitized by dyes with thiophene and benzene as it-linker possessed relative lower eta, 5.92% and 4.97%, respectively. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：407 / 413
页数：7
相关论文
共 34 条
[1]   High Molar Extinction Coefficient Branchlike Organic Dyes Containing Di(p-tolyl)phenylamine Donor for Dye-Sensitized Solar Cells Applications [J].
Chen, Huajie ;
Huang, Hui ;
Huang, Xianwei ;
Clifrord, John N. ;
Forneli, Amparo ;
Palomares, Emilio ;
Zheng, Xiaoyan ;
Zheng, Liping ;
Wang, Xianyou ;
Shen, Ping ;
Zhao, Bin ;
Tan, Songting .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (07) :3280-3286
[2]   Tetrahydroquinoline dyes with different spacers for organic dye-sensitized solar cells [J].
Chen, Ruikui ;
Yang, Xichuan ;
Tian, Haining ;
Sun, Licheng .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2007, 189 (2-3) :295-300
[3]   D-π-A Sensitizers for Dye-Sensitized Solar Cells: Linear vs Branched Oligothiophenes [J].
Fischer, Markus K. R. ;
Wenger, Sophie ;
Wang, Mingkui ;
Mishra, Amaresh ;
Zakeeruddin, Shaik M. ;
Gratzel, Michael ;
Baeuerle, Peter .
CHEMISTRY OF MATERIALS, 2010, 22 (05) :1836-1845
[4]   A novel organic chromophore for dye-sensitized nanostructured solar cells [J].
Hagberg, Daniel P. ;
Edvinsson, Tomas ;
Marinado, Tannia ;
Boschloo, Gerrit ;
Hagfeldt, Anders ;
Sun, Licheng .
CHEMICAL COMMUNICATIONS, 2006, (21) :2245-2247
[5]   Oligothiophene-containing coumarin dyes for efficient dye-sensitized solar cells [J].
Hara, K ;
Wang, ZS ;
Sato, T ;
Furube, A ;
Katoh, R ;
Sugihara, H ;
Dan-Oh, Y ;
Kasada, C ;
Shinpo, A ;
Suga, S .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (32) :15476-15482
[6]   Molecular design of coumarin dyes for efficient dye-sensitized solar cells [J].
Hara, K ;
Sato, T ;
Katoh, R ;
Furube, A ;
Ohga, Y ;
Shinpo, A ;
Suga, S ;
Sayama, K ;
Sugihara, H ;
Arakawa, H .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (02) :597-606
[7]   A coumarin-derivative dye sensitized nanocrystalline TiO2 solar cell having a high solar-energy conversion efficiency up to 5.6% [J].
Hara, K ;
Sayama, K ;
Ohga, Y ;
Shinpo, A ;
Suga, S ;
Arakawa, H .
CHEMICAL COMMUNICATIONS, 2001, (06) :569-570
[8]   High efficiency of dye-sensitized solar cells based on metal-free indoline dyes [J].
Horiuchi, T ;
Miura, H ;
Sumioka, K ;
Uchida, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (39) :12218-12219
[9]   A highly efficient organic sensitizer for dye-sensitized solar cells [J].
Hwang, Suyoung ;
Lee, Jung Ho ;
Park, Chanmoo ;
Lee, Hoinglae ;
Kim, Chaekyu ;
Park, Chiyoung ;
Lee, Mi-Hyeon ;
Lee, Wanin ;
Park, Jihee ;
Kim, Kyungkon ;
Park, Nam-Gyu ;
Kim, Chulhee .
CHEMICAL COMMUNICATIONS, 2007, (46) :4887-4889
[10]   Y-shaped dyes based on triphenylamine for efficient dye-sensitized solar cells [J].
Jia, Junhui ;
Cao, Kaiyu ;
Xue, Pengchong ;
Zhang, Yuan ;
Zhou, Huipeng ;
Lu, Ran .
TETRAHEDRON, 2012, 68 (18) :3626-3632
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