Ethynyl hydrogen bonds and iodoethynyl halogen bonds: a case of synthon mimicry

被引：20

作者：

Aakeroy, Christer B. ^{[1
]}

Welideniya, Dhanushi ^{[1
]}

Desper, John ^{[1
]}

机构：

[1] Kansas State Univ, Dept Chem, Manhattan, KS 66506 USA

来源：

CRYSTENGCOMM | 2017年 / 19卷 / 01期

关键词：

NONCOVALENT SYNTHESIS; ELECTROSTATICS; COMPLEXES;

D O I：

10.1039/c6ce02201d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The common electrostatic features of ethynyl and iodoethynyl hydrogen-and halogen-bond donors, respectively, lead to synthon mimicry which can be employed in synthetic crystal engineering for the construction of identical supramolecular assemblies in the solid-state.

引用

页码：11 / 13

页数：3

共 29 条

[11] Halogen bonding in solution [J].

Erdelyi, Mate .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (09) :3547-3557

[12] Hydrogen and halogen bonds are ruled by the same mechanisms [J].

Grabowski, Slawomir J. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (19) :7249-7259

[13] Is Electrostatics Sufficient to Describe Hydrogen-Bonding Interactions? [J].

Hoja, Johannes ;

Sax, Alexander F. ;

Szalewicz, Krzysztof .

CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (08) :2292-2300

[14]

Legon AC, 1999, ANGEW CHEM INT EDIT, V38, P2687

[15] The halogen bond: an interim perspective [J].

Legon, Anthony C. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (28) :7736-7747

[16] Halogen bonding based recognition processes: A world parallel to hydrogen bonding [J].

Metrangolo, P ;

Neukirch, H ;

Pilati, T ;

Resnati, G .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (05) :386-395

[17] A Molecular Electrostatic Potential Analysis of Hydrogen, Halogen, and Dihydrogen Bonds [J].

Mohan, Neetha ;

Suresh, Cherumuttathu H. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 118 (09) :1697-1705

[18] Halogen bonding and other σ-hole interactions: a perspective [J].

Politzer, Peter ;

Murray, Jane S. ;

Clark, Timothy .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (27) :11178-11189

[19] Halogen bonding: an electrostatically-driven highly directional noncovalent interaction [J].

Politzer, Peter ;

Murray, Jane S. ;

Clark, Timothy .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (28) :7748-7757

[20]

Prins LJ, 2001, ANGEW CHEM INT EDIT, V40, P2382, DOI 10.1002/1521-3773(20010702)40:13<2382::AID-ANIE2382>3.0.CO

← 1 2 3 →