Synthesis, characterization, and photophysical properties of covalent-linked ferrocene-porphyrin-single-walled carbon nanotube triad hybrid

被引：32
作者：
Zhao, Haiying [3 ]
Zhu, Yizhou [1 ,2 ]
Chen, Chen [1 ,2 ]
He, Lin [1 ,2 ]
Zheng, Jianyu [1 ,2 ]
机构：
[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
[3] Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China
来源：
CARBON | 2012年 / 50卷 / 13期
关键词：
PHOTOINDUCED ELECTRON-TRANSFER; SOLAR-ENERGY CONVERSION; CHARGE-SEPARATED STATE; FULLERENE; PHTHALOCYANINE; NANOHYBRIDS; EFFICIENT; HETEROJUNCTION; EXCITATION; DYADS;
D O I：
10.1016/j.carbon.2012.06.018
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The ferrocene-porphyrin-single-walled carbon nanotube (Fc-H2P-SWCNT) triad hybrid was prepared by amidation reaction between carboxylated SWCNT and aminoporphyrin bearing an appended ferrocenyl substituent. The hybrid described here was fully characterized by a combination of analytical techniques such as Fourier transform infrared spectroscopy, Raman, absorption and emission spectroscopy, atomic force and scanning electron microscopy, thermogravimetric analysis, and X-ray photoelectron spectroscopy. The steady emission characteristics revealed the existence of the effective photoinduced electron transfer among ferrocene, excited porphyrin moiety and SWCNT, which was further confirmed by the results of time-resolved transient absorption spectra. The final lifetime of charge-separation state was observed to be 62.9 mu s in N,N-dimethylformamide, which was significant increased compared to the reference nanohybrid porphyrin-SWCNT and the reported ferrocene-porphyrin-fullerene triad. Therefore, Fc-H2P-SWCNT triad hybrid constructed by amidation is rationally expected to be an improved photon-to-electron conversion system. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4894 / 4902
页数：9
相关论文
共 56 条
  • [1] Photoinduced processes in fullerenopyrrolidine and fullerenopyrazoline derivatives substituted with an oligophenylenevinylene moiety
    Armaroli, N
    Accorsi, G
    Gisselbrecht, JP
    Gross, M
    Krasnikov, V
    Tsamouras, D
    Hadziioannou, G
    Gómez-Escalonilla, MJ
    Langa, F
    Eckert, JF
    Nierengarten, JF
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) : 2077 - 2087
  • [2] Synthesis, characterization and photophysical properties of a SWNT-phthalocyanine hybrid
    Ballesteros, Beatriz
    Campidelli, Stephane
    de la Torre, Gema
    Ehli, Christian
    Guldi, Dirk M.
    Prato, Maurizio
    Torres, Tomas
    [J]. CHEMICAL COMMUNICATIONS, 2007, (28) : 2950 - 2952
  • [3] Panchromatic light harvesting in single wall carbon nanotube hybrids-immobilization of porphyrin-phthalocyanine conjugates
    Bartelmess, Juergen
    Soares, Ana R. M.
    Victoria Martinez-Diaz, M.
    Neves, Maria G. P. M. S.
    Tome, Augusto C.
    Cavaleiro, Jose A. S.
    Torres, Tomas
    Guldi, Dirk M.
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (12) : 3490 - 3492
  • [4] Dendrimer-functionalized single-wall carbon nanotubes: Synthesis, characterization, and photoinduced electron transfer
    Campidelli, Stephane
    Sooambar, Chloe
    Diz, Enrique Lozano
    Ehli, Christian
    Guldi, Dirk M.
    Prato, Maurizio
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (38) : 12544 - 12552
  • [5] Electronic Detection of Lectins Using Carbohydrate-Functionalized Nanostructures: Graphene versus Carbon Nanotubes
    Chen, Yanan
    Vedala, Harindra
    Kotchey, Gregg P.
    Audfray, Aymeric
    Cecioni, Samy
    Imberty, Anne
    Vidal, Sebastien
    Star, Alexander
    [J]. ACS NANO, 2012, 6 (01) : 760 - 770
  • [6] Supramolecular Functionalization of Single-Walled Carbon Nanotubes with Triply Fused Porphyrin Dimers: A Study of Structure-Property Relationships
    Cheng, Fuyong
    Zhu, Jason
    Adronov, Alex
    [J]. CHEMISTRY OF MATERIALS, 2011, 23 (13) : 3188 - 3194
  • [7] Supramolecular triads formed by axial coordination of fullerene to covalently linked zinc porphyrin-ferrocene(s): Design, syntheses, electrochemistry, and photochemistry
    D'Souza, F
    Smith, PM
    Gadde, S
    McCarty, AL
    Kullman, MJ
    Zandler, ME
    Itou, M
    Araki, Y
    Ito, O
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (31) : 11333 - 11343
  • [8] Self-assembled single-walled carbon nanotube:zinc-porphyrin hybrids through ammonium ion-crown ether interaction:: Construction and electron transfer
    D'Souza, Francis
    Chitta, Raghu
    Sandanayaka, Atula S. D.
    Subbaiyan, Navaneetha K.
    D'Souza, Lawrence
    Araki, Yasuyuki
    Ito, Osamu
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (29) : 8277 - 8284
  • [9] Bionano Donor-Acceptor Hybrids of Porphyrin, ssDNA, and Semiconductive Single-Wall Carbon Nanotubes for Electron Transfer via Porphyrin Excitation
    D'Souza, Francis
    Das, Sushanta K.
    Zandler, Melvin E.
    Sandanayaka, Atula S. D.
    Ito, Osamu
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (49) : 19922 - 19930
  • [10] Supramolecular donor-acceptor hybrids of porphyrins/phthalocyanines with fullerenes/carbon nanotubes: electron transfer, sensing, switching, and catalytic applications
    D'Souza, Francis
    Ito, Osamu
    [J]. CHEMICAL COMMUNICATIONS, 2009, (33) : 4913 - 4928
123456