Surface dealloyed PtCo nanoparticles supported on carbon nanotube: facile synthesis and promising application for anion exchange membrane direct crude glycerol fuel cell

被引:68
作者
Qi, Ji [1 ]
Xin, Le [1 ]
Zhang, Zhiyong [1 ]
Sun, Kai [2 ]
He, Haiying [3 ]
Wang, Fang [1 ]
Chadderdon, David [1 ]
Qiu, Yang [1 ]
Liang, Changhai [4 ]
Li, Wenzhen [1 ]
机构
[1] Michigan Technol Univ, Dept Chem Engn, Houghton, MI 49931 USA
[2] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA
[3] Michigan Technol Univ, Dept Phys, Houghton, MI 49931 USA
[4] Dalian Univ Technol, Sch Chem Engn, Dalian, Liaoning, Peoples R China
基金
美国国家科学基金会;
关键词
OXYGEN REDUCTION REACTION; ETHANOL OXIDATION REACTION; ALKALINE MEDIA; ELECTROCATALYTIC OXIDATION; ALCOHOL OXIDATION; CO NANOPARTICLES; BIOFUEL CELL; CATALYSTS; PALLADIUM; PERFORMANCE;
D O I
10.1039/c3gc36955b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Carbon nanotube-supported surface dealloyed PtCo nanoparticles are synthesized as highly active glycerol oxidation catalysts via a facile surfactant and thermo free process. The direct crude glycerol anion exchange membrane fuel cell using this nanocomposite as the anode catalyst (0.5 mg(Pt) cm(-2)) can achieve a peak power density of 268.5 mW cm(-2) at 80 degrees C and ambient pressure.
引用
收藏
页码:1133 / 1137
页数:5
相关论文
共 36 条
[1]   Complete Oxidation of Glycerol in an Enzymatic Biofuel Cell [J].
Arechederra, R. L. ;
Minteer, S. D. .
FUEL CELLS, 2009, 9 (01) :63-69
[2]   Development of glycerol/O2 biofuel cell [J].
Arechederra, Robert L. ;
Treu, Becky L. ;
Minteer, Shelley D. .
JOURNAL OF POWER SOURCES, 2007, 173 (01) :156-161
[3]  
Bambagioni V, 2010, CHIM OGGI, V28, pVII
[4]   Pd and Pt-Ru anode electrocatalysts supported on multi-walled carbon nanotubes and their use in passive and active direct alcohol fuel cells with an anion-exchange membrane (alcohol = methanol, ethanol, glycerol) [J].
Bambagioni, Valentina ;
Bianchini, Claudio ;
Marchionni, Andrea ;
Filippi, Jonathan ;
Vizza, Francesco ;
Teddy, Jacques ;
Serp, Philippe ;
Zhiani, Mohammad .
JOURNAL OF POWER SOURCES, 2009, 190 (02) :241-251
[5]   Palladium-Based Electrocatalysts for Alcohol Oxidation in Half Cells and in Direct Alcohol Fuel Cells [J].
Bianchini, Claudio ;
Shen, Pei Kang .
CHEMICAL REVIEWS, 2009, 109 (09) :4183-4206
[6]   Electrocatalyst approaches and challenges for automotive fuel cells [J].
Debe, Mark K. .
NATURE, 2012, 486 (7401) :43-51
[7]   Treatment of biodiesel production wastes with simultaneous electricity generation using a single-chamber microbial fuel cell [J].
Feng, Yujie ;
Yang, Qiao ;
Wang, Xin ;
Liu, Yankun ;
Lee, He ;
Ren, Nanqi .
BIORESOURCE TECHNOLOGY, 2011, 102 (01) :411-415
[8]   Reactive Depth and Performance of an Electrochemical Carbon Nanotube Network as a Function of Mass Transport [J].
Gao, Guandao ;
Vecitis, Chad D. .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (11) :6096-6103
[9]   Influence of operational parameters and of catalytic materials on electrical performance of Direct Glycerol Solid Alkaline Membrane Fuel Cells [J].
Ilie, A. ;
Simoes, M. ;
Baranton, S. ;
Coutanceau, C. ;
Martemianov, S. .
JOURNAL OF POWER SOURCES, 2011, 196 (11) :4965-4971
[10]   Fuels of the future [J].
Jang, Ben W. -L. ;
Glaeser, Roger ;
Dong, Mingdong ;
Liu, Chang-Jun .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (03) :253-253