The incomplete cubane complexes having Co3O4 or Mo3S4 core with the N-N-O type tridentates; L-histidinato and ethylenediamine-N-acetato

被引:16
|
作者
Ama, T [1 ]
Rashid, MM [1 ]
Sarker, AK [1 ]
Miyakawa, H [1 ]
Yonemura, T [1 ]
Kawaguchi, H [1 ]
Yasui, T [1 ]
机构
[1] Kochi Univ, Fac Sci, Dept Chem, Kochi 7808520, Japan
关键词
D O I
10.1246/bcsj.74.2327
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A trinuclear cobalt(III) complex, [Co-3(L-his)(3)(mu-OH)(3)(mu(3)-O)]ClO4.H2O (L-Hhis: L-histidine), containing an incomplete cubane Co3O4 core was isolated and the structure was compared with [Co-3(edma)(3)(mu-OH)(3)(mu(3)-O)](+) (Hedma: NH2CH2CH2NHCH2COOH) isomers. Using the edma and L-his as N-N-O type ligands, [Mo-3(L)(3)(mu-S)(3)(mu(3)-S)](+) complexes with a Mo3S4 incomplete cubane core were also prepared, and their structures were determined by the X-ray diffraction method. A structural similarity between [Mo-3(L)(3)(mu-S)(3)(mu(3)-S)](+) and [Co-3(L)(3)(mu-OH)(3)(mu(3)-O)](+) is discussed; it is suggested that three N-H...O inter-ligand (intra-molecular) attractive interaction has an important role in stabilizing the incomplete cubane structure.
引用
收藏
页码:2327 / 2333
页数:7
相关论文
共 50 条
  • [1] Synthesis and Crystal Structure of an Incomplete Cubane-type Mo3S4 Cluster with the N-N-O Type Tridentate Ligand: {Mo3S4[NH2CH2CH(O)CH2NH2]3}(DTP)·(H2O)2·(DMF)
    HU Rui-Feng QIN Ye-Yan KANG Yao ZHANG Jian WEN Yi-Hang LI Zhao-Ji CHEN Jiu-Tong YAO Yuan-Gen (State Key Laboratory of Structural Chemistry
    Chinese Journal of Structural Chemistry, 2005, (07) : 751 - 754
  • [2] Synthesis and crystal structure of an incomplete cubane-typeMo3S4 cluster with the N-N-O type tridentate ligand:: {Mo3S4[NH2CH2CH(O)CH2NH2]3}(DTP)•(H2O)2•(DMF)
    Hu, RF
    Qin, YY
    Kang, Y
    Zhang, J
    Wen, YH
    Li, ZJ
    Chen, JT
    Yao, YG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (07) : 751 - 754
  • [3] Optically active cobalt(III) complexes containing partial cubane Co3O4 core:: Syntheses and structures of the isomers of [Co3(L)3(μ-OH)3(μ3-O)]Cl (L = ethylenediamine-N-acetate)
    Ama, T
    Shiro, M
    Takeuchi, A
    Yonemura, T
    Kawaguchi, H
    Yasui, T
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (11) : 2685 - 2692
  • [4] TRINUCLEAR COBALT(III) COMPLEXES CONTAINING PARTIAL CUBANE CO3O4 CORE - SYNTHESIS AND STRUCTURE OF [CO-3(L)(3)(MU-OH)(3)(MU(3)-O)]CL (L=ETHYLENEDIAMINE-N-ACETATE)
    AMA, T
    MIYAZAKI, J
    HAMADA, K
    OKAMOTO, K
    YONEMURA, T
    KAWAGUCHI, H
    YASUI, T
    CHEMISTRY LETTERS, 1995, (04) : 267 - 268
  • [5] Poly[(μ3-N-acetyl-L-histidinato-κ4N,O:O:O′)silver(I)]
    Kasuga, Noriko C.
    Tsuruta, Shinichiro
    Amano, Akifumi
    Nomiya, Kenji
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M2440 - U1715
  • [6] Synthesis and Characterization of Oxygen/Sulfur-Bridged Incomplete Cubane-Type Clusters, [Mo3O n S4-n (Tm)3]+ (n=0-3)
    Akashi, Haruo
    Yoshida, Ryouichi
    Moriwaki, Kazuhiro
    Takagi, Hideaki
    Shibahara, Takashi
    JOURNAL OF CLUSTER SCIENCE, 2015, 26 (01) : 119 - 136
  • [7] Optically Active Cobalt(III) Complexes Containing Partial Cubane Co3O4 Core: Syntheses and Structures of the Isomers of [Co3(L)3(ae-@OH)3(ae3-@O)]Cl (L = Ethylenediamine-@N-@acetate)
    Ama, T.
    Shiro, M.
    Takeuchi, A.
    Yonemura, T.
    Bulletin of the Chemical Society of Japan, 1997, 70 (11)
  • [8] XPS SPECTRA OF INCOMPLETE CUBANE-TYPE CLUSTER WITH MO3O4-0-4S-O-4(4+)CORE
    SHIBAHARA, T
    TSURU, H
    KUROYA, H
    INORGANICA CHIMICA ACTA, 1988, 150 (02) : 167 - 168
  • [9] Cobalt(III) complexes containing incomplete C3O4 or complete Co4O4 cubane core
    Ama, T
    Rashid, MM
    Yonemura, T
    Kawaguchi, H
    Yasui, T
    COORDINATION CHEMISTRY REVIEWS, 2000, 198 : 101 - 116
  • [10] Revolutionizing n-type Co3O4 Nanowire for Hydrogen Gas Sensing
    Kumarage, Gayan W. C.
    Zappa, Dario
    Mihalcea, Catalina G. G.
    Maraloiu, Valentin-Adrian
    Stefan, Mariana
    Comini, Elisabetta
    ADVANCED ENERGY AND SUSTAINABILITY RESEARCH, 2023, 4 (10):