Synthesis, crystal structure, and magnetic properties of two bent trinuclear Cu(II)/Ni(II) complexes of ligands derived from N-acyl-salicylhydrazides

被引：11
|
作者：
Luo, Wei [1 ]
Wang, Xiu-Teng [2 ]
Meng, Xiang-Gao [3 ]
Cheng, Gong-Zhen [1 ]
Ji, Zhen-Ping
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
[3] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 09期
关键词：
trinuclear; bent; X-ray structure; magnetism;
D O I：
10.1016/j.inoche.2008.05.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two bent trinuclear Cu(II)/Ni(II) complexes [Cu-3(L-1)(2)(py)(2)] (1) and [Ni-3(L-2)(2)(py)(4)]center dot DMF (2), where H3L1 = N-(3,5-dimethylbenzoyl)-5-bromosalicylhydrazide, H3L2 = N-(3,5-dimethyl benzoyl)-salicylhydrazide, were synthesized and structurally characterized. In complex 1, all three Cu(II) ions take distorted planar square geometry. while in complex 2, the two terminal Ni(II) ions are distorted planar square, the central Ni(II) ion is octahedral. The magnetism of complex 1 was also studied. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：1044 / 1047
页数：4
相关论文
共 50 条
  • [41] Cyano-bridged heterotrinuclear molybdenum(IV)-nickel(II) complexes: Synthesis, crystal structure and magnetic properties
    Si, SF
    Liu, X
    Liao, DZ
    Yan, SP
    Jiang, ZH
    Cheng, P
    JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (04) : 337 - 341
  • [42] Synthesis, Crystal Structure and Magnetic Properties of an Oxalato- and Oxamido-bridged One-dimensional Mn(II)-Cu(II) Complex
    Hu Kong-Qiu
    Kou Hui-Zhong
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2012, 33 (05): : 892 - 896
  • [43] Synthesis, crystal structure and catecholase activity of a Ni(II) complex derived from a tetradentate Schiff base ligand
    PRADIPTA KUMAR BASU
    MERRY MITRA
    AMRITA GHOSH
    LATIBUDDIN THANDER
    CHIA -HER LIN
    RAJARSHI GHOSH
    Journal of Chemical Sciences, 2014, 126 : 1635 - 1640
  • [44] A new Salen-type azo-azomethine ligand and its Ni(II), Cu(II) and Zn(II) complexes: Synthesis, spectral characterization, crystal structure and photoluminescence studies
    Ozkan, Gozde
    Kose, Muhammet
    Zengin, Huseyin
    McKee, Vickie
    Kurtoglu, Mukerrem
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 150 : 966 - 973
  • [45] A Trinuclear Ni(II) Mixed-ligand Complex Containing Pentadentate N-butyl-salicylhydrazide and Monodentate Imidazole: Synthesis, Characterization and Crystal Structure
    Chen Xiao-Hua
    Wu Qiong-Jie
    Lv Wei
    Yang Ming-Xing
    Chen Li-Juan
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 32 (08) : 1117 - 1122
  • [46] Synthesis, spectral and magnetic properties of two different 2-nitrobenzoatocopper(II) complexes containing N,N-diethylnicotinamide
    Kavalirova, J.
    Korabik, M.
    Stachova, P.
    Moncol, J.
    Sillanpaa, R.
    Lis, T.
    Miklos, D.
    Melnik, M.
    Mroziniski, J.
    Valigura, D.
    POLYHEDRON, 2008, 27 (05) : 1333 - 1342
  • [47] Synthesis and Antimicrobial Studies of Cu(II), Ni(II) and Zn(II) Schiff Base Complexes Derived from Substituted 1,2,4-Triazoles and Heteroaromatic Aldehydes
    Zabin, Sami A.
    ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (09) : 4067 - 4071
  • [48] Tetranuclear manganese(II) complexes of hydrazone and carbohydrazone ligands: Synthesis, crystal structures, magnetic properties, Hirshfeld surface analysis and DFT calculations
    Abedi, Marjan
    Yesilel, Okan Zafer
    Mahmoudi, Ghodrat
    Bauza, Antonio
    Lofland, Samuel E.
    Yerli, Yusuf
    Kaminsky, Werner
    Garczarek, Piotr
    Zareba, Jan K.
    Ienco, Andrea
    Frontera, Antonio
    Gargari, Masoumeh Servati
    INORGANICA CHIMICA ACTA, 2016, 443 : 101 - 109
  • [49] Dinuclear triply bridged copper(II)-carboxylato compounds with different bischelating ligands: Synthesis, crystal structure, spectroscopic and magnetic properties
    Chailuecha, Chatkaew
    Youngme, Sujittra
    Pakawatchai, Chaveng
    Chaichit, Narongsak
    van Albada, Gerard A.
    Reedijk, Jan
    INORGANICA CHIMICA ACTA, 2006, 359 (13) : 4168 - 4178
  • [50] COMPLEXES WITH MACROCYCLIC LIGANDS .2. SYNTHESIS, STRUCTURE AND ELECTROCHEMICAL PROPERTIES OF A MACROCYCLIC CU2(II)MN(II) COMPLEX OF SCHIFF-BASE TYPE
    BRYCHCY, K
    JENS, KJ
    TILSET, M
    BEHRENS, U
    CHEMISCHE BERICHTE-RECUEIL, 1994, 127 (06): : 991 - 995
12345