Synthesis, crystal structure, and magnetic properties of two bent trinuclear Cu(II)/Ni(II) complexes of ligands derived from N-acyl-salicylhydrazides

被引：11
|
作者：
Luo, Wei [1 ]
Wang, Xiu-Teng [2 ]
Meng, Xiang-Gao [3 ]
Cheng, Gong-Zhen [1 ]
Ji, Zhen-Ping
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
[3] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 09期
关键词：
trinuclear; bent; X-ray structure; magnetism;
D O I：
10.1016/j.inoche.2008.05.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two bent trinuclear Cu(II)/Ni(II) complexes [Cu-3(L-1)(2)(py)(2)] (1) and [Ni-3(L-2)(2)(py)(4)]center dot DMF (2), where H3L1 = N-(3,5-dimethylbenzoyl)-5-bromosalicylhydrazide, H3L2 = N-(3,5-dimethyl benzoyl)-salicylhydrazide, were synthesized and structurally characterized. In complex 1, all three Cu(II) ions take distorted planar square geometry. while in complex 2, the two terminal Ni(II) ions are distorted planar square, the central Ni(II) ion is octahedral. The magnetism of complex 1 was also studied. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：1044 / 1047
页数：4
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