Photoreaction of C-60 with NTO (5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one)

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作者：
Pace, MD
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来源：
PROCEEDINGS OF THE SYMPOSIUM ON RECENT ADVANCES IN THE CHEMISTRY AND PHYSICS OF FULLERENES AND RELATED MATERIALS, VOL 3 | 1996年 / 96卷 / 10期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A photochemical free radical was detected from mixtures of C-60 in solution with 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one (NTO), which is a new energetic material compound. Reaction of an NTO anion radical with C-60 is suggested. An NTO-. anion radical is formed by reduction with electron donors, and NTO in protic solvents has been shown to form an NTO+. cation radical during photolysis. A free radical was also detected from photochemical reaction of C-60 with 9,10-dihyrdoanthracene, as a model compound.
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页码：223 / 227
页数：5
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