Photoreaction of C-60 with NTO (5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one)

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Pace, MD
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O64 [物理化学(理论化学)、化学物理学];
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070304 ; 081704 ;
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A photochemical free radical was detected from mixtures of C-60 in solution with 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one (NTO), which is a new energetic material compound. Reaction of an NTO anion radical with C-60 is suggested. An NTO-. anion radical is formed by reduction with electron donors, and NTO in protic solvents has been shown to form an NTO+. cation radical during photolysis. A free radical was also detected from photochemical reaction of C-60 with 9,10-dihyrdoanthracene, as a model compound.
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页码:223 / 227
页数:5
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