Self-assembled energetic 3D metal-organic framework [Na8(N5)8(H2O)3]n based on cyclo-N5-

被引：81

作者：

Xu, Yuangang ^{[1
]}

Wang, Pengcheng ^{[1
]}

Lin, Qiuhan ^{[1
]}

Mei, Xuefeng ^{[2
]}

Lu, Ming ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Xiaolingwei 200, Nanjing 210094, Jiangsu, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Mat Med, Pharmaceut Analyt & Solid State Chem Res Ctr, Shanghai 201203, Peoples R China

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 05期

基金：

中国国家自然科学基金;

关键词：

DETONATION PERFORMANCES; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; DENSITY MATERIAL; CO2; BINDING; NITROGEN; MOFS; EXPLOSIVES; CHEMISTRY; PENTAZOLATE;

D O I：

10.1039/c7dt04501h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

From a 1D sodium-N-5(-) framework, a new zeolite-like metalorganic framework (MOF) with a fascinating 3D structure was successfully constructed. It exhibited an enhanced thermal stability with a decomposition temperature (onset) of 129 degrees C and an enhanced coordination ability (five-coordination) of cyclo-N-5(-) in weak alkaline conditions. The 3D MOF with a bulky size offers new opportunities not only for the formation of porous materials but also to control the balance between the performance and stability of polynitrogen materials.

引用

页码：1398 / 1401

页数：4

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