Preparation of SO42-/Fe2O3-TiO2-Nd2O3 Solid Acid and its Activity for the Synthesis of Menthyl Acetate

被引：0
作者：
Yang, Chunhua [1 ]
Fan, Meiqing
Chen, Gang
Zhang, Long [1 ,2 ]
机构：
[1] NE Normal Univ, Sch Chem, Changchun 130024, Peoples R China
[2] Changchun Univ Technol, Sch Chem Engn, Changchun 130012, Peoples R China
来源：
JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN | 2012年 / 34卷 / 01期
关键词：
SULFATED ZIRCONIA; NMR;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This paper reports the preparation of SO42-/ Fe2O3-TiO2-Nd2O3(designated as SFTN) by combustion method, which were characterized by FT-IR and NH3-TPD techniques respectively. The results showed that SFTN kept the typical covalence S=O bond structure of SO42-/MxOy(SM)solid acids,and both Lewis and Bronsted acid sites existed; SFTN exhibited higher activity for the esterification of acetic acid and menthol, with 98.30% yield of mehthyl acetate. The higher activity was attribute to the enhancement of acidic properties of the catalyst by the addition of Nd2O3 to SO42-/ Fe2O3-TiO2 (SFT).
引用
收藏
页码：72 / 75
页数：4
相关论文
共 50 条
  • [41] Comparative study of aerogels nanostructured catalysts: Ni/ZrO2–SO42− and Ni/ZrO2–Al2O3–SO42−
    N. Kamoun
    M. K. Younes
    A. Ghorbel
    A. S. Mamede
    A. Rives
    [J]. Ionics, 2015, 21 : 221 - 229
  • [42] Synthesis and characterization of pure P2-and O3-Na2/3Fe2/3Mn1/3O2 as cathode materials for Na ion batteries
    Gonzalo, E.
    Han, M. H.
    Lopez del Amo, J. M.
    Acebedo, B.
    Casas-Cabanas, M.
    Rojo, T.
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (43) : 18523 - 18530
  • [43] Synthesis of dithiophosphoric acid derivatives with -SO2-OH and -O-SO2-OH functions
    Jullien, Y
    Georges, J
    Sindt, M
    Schneider, M
    Mieloszynski, JL
    Paquer, D
    [J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1998, 134 : 137 - 149
  • [44] Hydroisomerization of Benzene-Containing Gasoline Fractions on a Pt/-SO42--ZrO2-Al2O3 Catalyst: I. Effect of Chemical Composition on the Phase State and Texture Characteristics of SO42--ZrO2-Al2O3 Supports
    Kazakov, M. O.
    Lavrenov, A. V.
    Mikhailova, M. S.
    Allert, N. A.
    Gulyaeva, T. I.
    Muromtsev, I. V.
    Drozdov, V. A.
    Duplyakin, V. K.
    [J]. KINETICS AND CATALYSIS, 2010, 51 (03) : 438 - 443
  • [45] Scattering Effect of Iron Metallic Particles on the Extinction Coefficient of CaO-SiO2-B2O3-Na2O-Fe2O3-CaF2 Glasses
    Yoon, Dae-Woo
    Cho, Jung-Wook
    Kim, Seon-Hyo
    [J]. METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2016, 47 (05): : 2785 - 2792
  • [46] High-entropy R2O3-Y2O3-TiO2-ZrO2-Al2O3 glasses with ultrahigh hardness, Young's modulus, and indentation fracture toughness
    Guo, Yongchang
    Li, Jianqiang
    Zhang, Ying
    Feng, Shaowei
    Sun, Hong
    [J]. ISCIENCE, 2021, 24 (07)
  • [47] The solvothermal synthesis, structure and properties of Al2O3•TiO2 mesoporous material
    Guo Changyou
    Shen Zhiqi
    Hu Qi
    Wang Shaojun
    Ling Fengxiang
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2015, 151 : 288 - 294
  • [48] Preparation of Styrenated Phenol Over SO42-/ZrO2 Catalyst in a Large-Scale Synthesis Process
    Kwon, Yongchul
    Chung, Minchul
    Wonbong, Kwak
    Jung, Sunghun
    Ahn, Ho-Geun
    [J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2019, 19 (02) : 1196 - 1199
  • [49] New catalyst of SO42−/Al2O3–ZrO2 for n-butane isomerization
    Zi Gao
    Yongde Xia
    Weiming Hua
    Changxi Miao
    [J]. Topics in Catalysis, 1998, 6 : 101 - 106
  • [50] Effect of Fe2O3 on the Structure, Physical Properties and Crystallization of CaO-Al2O3-SiO2 Glass
    Zhang, Feng
    Xiong, Dehua
    Xie, Jun
    Zhang, Jihong
    Han, Jianjun
    Chen, Dequan
    Wen, Zhongquan
    Fan, Zhenhua
    Chen, Lina
    Sun, Tengfei
    [J]. JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2024, 39 (04): : 954 - 961
12345