Preparation of SO42-/Fe2O3-TiO2-Nd2O3 Solid Acid and its Activity for the Synthesis of Menthyl Acetate

被引：0

作者：

Yang, Chunhua ^{[1
]}

Fan, Meiqing

Chen, Gang

Zhang, Long ^{[1
,2
]}

机构：

[1] NE Normal Univ, Sch Chem, Changchun 130024, Peoples R China

[2] Changchun Univ Technol, Sch Chem Engn, Changchun 130012, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN | 2012年 / 34卷 / 01期

关键词：

SULFATED ZIRCONIA; NMR;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper reports the preparation of SO42-/ Fe2O3-TiO2-Nd2O3(designated as SFTN) by combustion method, which were characterized by FT-IR and NH3-TPD techniques respectively. The results showed that SFTN kept the typical covalence S=O bond structure of SO42-/MxOy(SM)solid acids,and both Lewis and Bronsted acid sites existed; SFTN exhibited higher activity for the esterification of acetic acid and menthol, with 98.30% yield of mehthyl acetate. The higher activity was attribute to the enhancement of acidic properties of the catalyst by the addition of Nd2O3 to SO42-/ Fe2O3-TiO2 (SFT).

引用

页码：72 / 75

页数：4

共 50 条

[1] Preparation and characterization of SO4 2-/Fe2O3-TiO2-Nd2O3 catalyst
Yang, C. H.
Fan, M. Q.
Chen, G.
Zhang, L.
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2013, 10 (03) : 407 - 413
[2] Synthesis of SO42-/TiO2-ZnAl2O4 composite solid acids as the esterification catalysts
Wang, An-Qi
Wang, Jun-Xia
Wang, Hui
Huang, Ya-Nan
Xu, Ming-Liang
Wu, Xiu-Ling
RSC ADVANCES, 2017, 7 (23): : 14224 - 14232
[3] Designed SO42-/Fe2O3-SiO2 solid acids for polyoxymethylene dimethyl ethers synthesis: The acid sites control and reaction pathways
Li, Huaju
Song, Huanling
Chen, Liwei
Xia, Chungu
APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 165 : 466 - 476
[4] Isomerization of n-hexane on Pd/SO42-/ZrO2/Al2O3 and mechanical mixtures Pd/Al2O3 (Pd/SiO2) + SO42-/ZrO2/Al2O3
Dzhikiya, O., V
Smolikov, M. D.
Zatolokina, E., V
Kazantsev, K., V
Belyi, A. S.
OIL AND GAS ENGINEERING (OGE-2016), 2016, 152 : 116 - 121
[5] Chlorinated volatile organic compound oxidation over SO42-/Fe2O3 catalysts
Zhang, Zhen
Huang, Ju
Xia, Hangqi
Dai, Qiguang
Gu, Yufeng
Lao, Yijie
Wang, Xingyi
JOURNAL OF CATALYSIS, 2018, 360 : 277 - 289
[6] Preparation, Surface Acidity and Catalytic Esterification Activity of Solid Acid S2O82-/TiO2-La2O3
He, Jie-Yu
Wang, Hui
Liao, De-Zhong
Jin, Yun-Kang
PROCEEDINGS OF THE 4TH 2016 INTERNATIONAL CONFERENCE ON MATERIAL SCIENCE AND ENGINEERING (ICMSE 2016), 2016, 101 : 98 - 104
[7] Catalytic conversion of xylose to furfural over the solid acid SO42-/ZrO2-Al2O3/SBA-15 catalysts
Shi, Xuejun
Wu, Yulong
Li, Panpan
Yi, Huaifeng
Yang, Mingde
Wang, Gehua
CARBOHYDRATE RESEARCH, 2011, 346 (04) : 480 - 487
[8] Synthesis, characterization and activity study of SO42-/CexZr1-x O2 solid superacid catalyst
Reddy, BM
Sreekanth, PM
Lakshmanan, P
Khan, A
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 244 (1-2) : 1 - 7
[9] New catalyst of SO42-/Al2O3-ZrO2 for n-butane isomerization
Gao, Z
Xia, YD
Hua, WM
Miao, CX
TOPICS IN CATALYSIS, 1998, 6 (1-4) : 101 - 106
[10] Synthesis of Brominated Alkanes via Heterogeneous Catalytic Distillation over Al2O3/SO42-/ZrO2
Yang, Su
Guo, Xiaoxuan
Pan, Xiaomei
Gu, Liuyu
Liu, Xueping
Gao, Lijing
Xiao, Guomin
CATALYSTS, 2021, 11 (12)

← 1 2 3 4 5 →