Detection of bisphenol A in food packaging based on fluorescent conjugated polymer PPESO3 and enzyme system

被引:28
作者
Huang, Hui [1 ,2 ]
Li, Yongxin [3 ]
Liu, Jintong [2 ]
Tong, Jin [1 ]
Su, Xingguang [2 ]
机构
[1] Jilin Univ, Coll Biol & Agr Engn, Changchun 130025, Peoples R China
[2] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
Water-soluble conjugated polymer; Enzyme hybrid system; Bisphenol A; LIQUID-CHROMATOGRAPHY; SENSITIVE DETERMINATION; WATER; CHEMILUMINESCENCE; SENSOR; POLYELECTROLYTE; LABEL; CELLS; BPA;
D O I
10.1016/j.foodchem.2015.03.076
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Bisphenol A (BPA) is a kind of carcinogen, which can interfere with the body's endocrine system. In this paper, a new kind of fluorescent sensor for BPA detection was established based on the fluorescent conjugated polymer PPESO3. The oxidative product of BPA is able to quench PPESO3 in the presence of HRP and H2O2, and the quenched PL intensity of PPESO3 was proportionally to the concentration of BPA in the range of 1-100 mu mol/L with a detection limit of 4 x 10(-7) mol/L. The proposed method has been applied to detect BPA in eight food packaging samples with satisfactory results. The proposed method has the potential for the assay of BPA in food or food packaging samples. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:233 / 238
页数:6
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