Microwave Synthesis of the CPM-5 Metal Organic Framework

被引：67

作者：

Sabouni, Rana ^{[1
]}

Kazemian, Hossein ^{[1
]}

Rohani, Sohrab ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem & Biochem Engn, London, ON N6A 5B9, Canada

来源：

CHEMICAL ENGINEERING & TECHNOLOGY | 2012年 / 35卷 / 06期

关键词：

Carbon dioxide adsorption; CPM-5; Indium metal organic framework; Microwave; Particle size; Surface area; CHROMIUM TEREPHTHALATE MIL-101; CARBON-DIOXIDE CAPTURE; RAPID PRODUCTION; CO2; SEQUESTRATION; ULTRASOUND; SORPTION;

D O I：

10.1002/ceat.201100626

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The metal organic framework CPM-5 (crystalline porous materials) was successfully synthesized and characterized for the first time using microwave irradiation as a rapid and facile synthesis method in about 10?min compared to several days crystallization time required for the conventional solvothermal approaches. Furthermore, CPM-5 produced by microwave-assisted synthesis exhibited a very high surface area of 2187?m2g1 compared to, e.g., 580?m2g1 of the conventionally synthesized samples. Moreover, the as-synthesized CPM-5 showed high carbon dioxide uptake.

引用

页码：1085 / 1092

页数：8

共 29 条

[1]

[Anonymous], 2010, INT EN OUTL 2010

[2]

Choi JY, 2006, B KOREAN CHEM SOC, V27, P1523

[3] Metal-organic framework MOF-5 prepared by microwave heating: Factors to be considered [J].

Choi, Jung-Sik ;

Son, Won-Jin ;

Kim, Jahoen ;

Ahn, Wha-Seung .

MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 116 (1-3) :727-731

[4] Toward carbon dioxide capture using nanoporous materials [J].

D'Alessandro, Deanna M. ;

McDonald, Thomas .

PURE AND APPLIED CHEMISTRY, 2011, 83 (01) :57-66

[5] A chromium terephthalate-based solid with unusually large pore volumes and surface area [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F ;

Dutour, J ;

Surblé, S ;

Margiolaki, I .

SCIENCE, 2005, 309 (5743) :2040-2042

[6] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

[7] Enhanced hydrogen production from biomass with in situ carbon dioxide capture using calcium oxide sorbents [J].

Florin, Nicholas H. ;

Harris, Andrew T. .

CHEMICAL ENGINEERING SCIENCE, 2008, 63 (02) :287-316

[8] Synthesis of a Metal-Organic Framework Material, Iron Terephthalate, by Ultrasound, Microwave, and Conventional Electric Heating: A Kinetic Study [J].

Haque, Enamul ;

Khan, Nazmul Abedin ;

Park, Jung Hwa ;

Jhung, Sung Hwa .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (03) :1046-1052

[9] Porous Chromium Terephthalate MIL-101 with Coordinatively Unsaturated Sites: Surface Functionalization, Encapsulation, Sorption and Catalysis [J].

Hong, Do-Young ;

Hwang, Young Kyu ;

Serre, Christian ;

Ferey, Gerard ;

Chang, Jong-San .

ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (10) :1537-1552

[10] Crystal morphology control of AFI type molecular sieves with microwave irradiation [J].

Jhung, SH ;

Chang, JS ;

Hwang, YK ;

Park, SE .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (02) :280-285

← 1 2 3 →