Transition-metal-mediated rational design and self-assembly of chiral, nanoscale supramolecular polyhedra with unique T symmetry

被引：143

作者：

Stang, PJ ^{[1
]}

Olenyuk, B ^{[1
]}

Muddiman, DC ^{[1
]}

Smith, RD ^{[1
]}

机构：

[1] PACIFIC NW NATL LAB, MACROMOL STRUCT & DYNAM DIV, ENVIRONM MOL SCI LAB, RICHLAND, WA 99352 USA

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 14期

关键词：

D O I：

10.1021/om9702993

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel family of chiral, discrete, nanoscale-sized supramolecular cages are prepared, via self-assembly and noncovalent interactions from the tridentate ligand 1,3,5-tris[(4-pyridyl)ethynyl]benzene and [(R)-(+)-BINAP]Pd-II and -Pt-II bis(triflates). The cationic parts of these highly symmetrical species possess large three-dimensional cavities and are rare examples of molecules with T symmetry.

引用

页码：3094 / 3096

页数：3

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