Comparison of real waste (MSW and MPW) pyrolysis in batch reactor over different catalysts. Part II: Contaminants, char and pyrolysis oil properties

被引：91

作者：

Miskolczi, Norbert ^{[1
]}

Ates, Funda ^{[2
]}

Borsodi, Nikolett ^{[1
]}

机构：

[1] Univ Pannonia, MOL Dept Hydrocarbon & Coal Proc, H-8200 Veszprem, Hungary

[2] Anadolu Univ, Fac Engn, Dept Chem Engn, TR-26555 Eskisehir, Turkey

来源：

BIORESOURCE TECHNOLOGY | 2013年 / 144卷

关键词：

Pyrolysis; Double bond isomerization; Contaminants; Catalysts; BIO-OIL; VACUUM PYROLYSIS; CO-PYROLYSIS; BIOMASS; FUEL; POLYMERS; PLASTICS; BIOCHAR; QUALITY; BARK;

D O I：

10.1016/j.biortech.2013.06.109

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

Pyrolysis of real wastes (MPW and MSW) has been investigated at 500 degrees C, 550 degrees C and 600 degrees C using Y-zeolite, beta-zeolite, equilibrium FCC, MoO3, Ni-Mo-catalyst, HZSM-5 and Al(OH)(3) as catalysts. The viscosity of pyrolysis oils could be decreased by the using of catalysts, especially by beta-zeolite and MoO3. Both carbon frame and double bound isomerization was found in case of thermo-catalytic pyrolysis. Char morphology and texture analysis showed more coke deposits on the catalyst surface using MSW raw material. Pyrolysis oils had K, S. P Cl, Ca, Zn, Fe, Cr, Br and Sb as contaminants; and the concentrations of K, S. P, Cl and Br could be decreased by the using of catalysts. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：370 / 379

页数：10

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