Oxidation of Benzyl Halides to Aldehydes and Ketones with Potassium Nitrate Catalyzed by Phase-Transfer Catalyst in Aqueous Media

被引：14

作者：

Liu, Qifa ^{[1
]}

Lu, Ming ^{[1
]}

Sun, Feng ^{[2
]}

Li, Jiang ^{[1
]}

Zhao, Yuebing ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Chem Engn Coll, Nanjing 210094, Peoples R China

[2] Nanjing Cosmos Chem Co, Nanjing, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 23期

关键词：

Benzyl halide; oxidation; phase-transfer catalyst; potassium nitrate;

D O I：

10.1080/00397910802323080

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalytic oxidation of benzyl halides to aldehydes and ketones in aqueous media was studied under relatively mild reaction conditions by using phase-transfer catalyst combined with potassium nitrate and 10% aqueous potassium hydroxide solution. As a result, a simple high-yield procedure has been developed.

引用

页码：4188 / 4197

页数：10

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