High resolution electron energy loss spectroscopy study of Zinc phthalocyanine and tetrafluoro tetracyanoquinodimethane on Au (111)

被引:7
作者
Lu, Jiong [1 ]
Loh, Kian Ping [1 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
关键词
LIGHT-EMITTING-DIODES; VIBRATIONAL SPECTROSCOPY; TETRAFLUOROTETRACYANOQUINODIMETHANE; TRANSISTORS; FILMS; CRYSTALS; AG(110); PHYSICS; TCNQF4; PTCDA;
D O I
10.1016/j.cplett.2008.11.076
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using high resolution electron energy loss spectroscopy, we have examined the vibrational and electronic information of Zinc phthalocyanine (ZnPc) and tetrafluoro tetracyanoquinodimethane (F4-TCNQ) on Au (1 1 1). The changes in the vibrational loss features reveal distinct changes in growth modes at different film thickness as well as occurrence of charge transfer between adsorbate and substrate. Up to a thickness of 10 monolayers, ZnPc film grows with its molecular plane parallel to the substrate. After the introduction of small quantities of F4-TCNQ on ZnPc film, evidence of p-doping can be seen from the red shift of C N stretching in F4-TCNQ. (C) 2008 Elsevier B. V. All rights reserved.
引用
收藏
页码:28 / 31
页数:4
相关论文
共 38 条
[1]  
[Anonymous], 1992, PHTHALOCYANINES PROP
[2]   The copper phthalocyanine/Au(100) interface studied using high resolution electron energy-loss spectroscopy [J].
Auerhammer, JM ;
Knupfer, M ;
Peisert, H ;
Fink, J .
SURFACE SCIENCE, 2002, 506 (03) :333-338
[3]   Characterization of thin films of chloroaluminum phthalocyanine on MoS2:: HREELS, LEET and PIES study [J].
Azuma, Y ;
Yokota, T ;
Kera, S ;
Aoki, M ;
Okudaira, KK ;
Harada, Y ;
Ueno, N .
THIN SOLID FILMS, 1998, 327 :303-307
[4]   Vibrational spectroscopy of phthalocyanine and naphthalocyanine in sandwich-type (na)phthalocyaninato and porphyrinato rare earth complexes (Part 10) The infrared and Raman characteristics of phthalocyanine in heteroleptic bis(phthalocyaninato) rare earth complexes with decreased molecular symmetry [J].
Bao, M ;
Bian, YZ ;
Rintoul, L ;
Wang, RM ;
Arnold, DP ;
Ma, CQ ;
Jiang, JZ .
VIBRATIONAL SPECTROSCOPY, 2004, 34 (02) :283-291
[5]   Low voltage organic light emitting diodes featuring doped phthalocyanine as hole transport material [J].
Blochwitz, J ;
Pfeiffer, M ;
Fritz, T ;
Leo, K .
APPLIED PHYSICS LETTERS, 1998, 73 (06) :729-731
[6]   Interface electronic structure of organic semiconductors with controlled doping levels [J].
Blochwitz, J. ;
Fritz, T. ;
Pfeiffer, M. ;
Leo, K. ;
Alloway, D. M. ;
Lee, P. A. ;
Armstrong, N. R. .
ORGANIC ELECTRONICS, 2001, 2 (02) :97-104
[7]   Device physics of polymer:fullerene bulk heterojunction solar cells [J].
Blom, Paul W. M. ;
Mihailetchi, Valentin D. ;
Koster, L. Jan Anton ;
Markov, Denis E. .
ADVANCED MATERIALS, 2007, 19 (12) :1551-1566
[8]   Mapping surface plasmons at the nanometre scale with an electron beam [J].
Bosman, Michel ;
Keast, Vicki J. ;
Watanabe, Masashi ;
Maaroof, Abbas I. ;
Cortie, Michael B. .
NANOTECHNOLOGY, 2007, 18 (16)
[9]   Large-scale complementary integrated circuits based on organic transistors [J].
Crone, B ;
Dodabalapur, A ;
Lin, YY ;
Filas, RW ;
Bao, Z ;
LaDuca, A ;
Sarpeshkar, R ;
Katz, HE ;
Li, W .
NATURE, 2000, 403 (6769) :521-523
[10]   Calculation of the structure and absorption spectra of phthalocyanines in the gas-phase and in solution [J].
Day, PN ;
Wang, ZQ ;
Pachter, R .
THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE, 1998, 455 (01) :33-50