Raman scattering and photoluminescence analysis of B-doped CdS thin films

被引:93
作者
Lee, J [1 ]
机构
[1] Kunsan Natl Univ, Sch Elect & Informat Engn, Kunsan, Chonbuk, South Korea
关键词
cadmium sulfide; boron; Raman scattering; solar cells;
D O I
10.1016/j.tsf.2003.10.103
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Boron-doped US thin films were chemically deposited onto glass substrates. X-Ray diffraction (XRD), photoluminescence (PL), and Raman techniques were used to evaluate the quality of B-doped US films. XRD results have confirmed that B-doped US films have a hexagonal structure with a preferential orientation of the (002) plane. The grain size of B-doped US films slightly decreases, but no change of the microstructure was observed. The PL spectra for all samples consist of two prominent broad bands approximately 2.3 eV (green emission) and 1.6 eV (red emission) and the higher doping concentrations gradually decreased the green emission and red emission. Raman analysis has shown that undoped films have structure superior to those of B-doped US films. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:170 / 174
页数:5
相关论文
共 21 条
[1]   PHOTOLUMINESCENCE SPECTRA OF GAS-EVAPORATED CDS MICROCRYSTALS [J].
AGATA, M ;
KURASE, H ;
HAYASHI, S ;
YAMAMOTO, K .
SOLID STATE COMMUNICATIONS, 1990, 76 (08) :1061-1065
[2]   Novel approach to the deposition of CdS by chemical bath deposition: the deposition of crystalline thin films of CdS from acidic baths [J].
Boyle, DS ;
O'Brien, P ;
Otway, DJ ;
Robbe, O .
JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (03) :725-729
[3]   PIEZOSPECTROSCOPIC STUDY OF RAMAN-SPECTRUM OF CADMIUM-SULFIDE [J].
BRIGGS, RJ ;
RAMDAS, AK .
PHYSICAL REVIEW B, 1976, 13 (12) :5518-5529
[4]   SOLUTION-GROWN CADMIUM-SULFIDE FILMS FOR PHOTOVOLTAIC DEVICES [J].
CHU, TL ;
CHU, SS ;
SCHULTZ, N ;
WANG, C ;
WU, CQ .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (09) :2443-2446
[5]   RAMAN INVESTIGATIONS OF THE SURFACE-MODES OF THE CRYSTALLITES IN CDS THIN-FILMS GROWN BY PULSED LASER AND THERMAL EVAPORATION [J].
CHUU, DS ;
DAI, CM ;
HSIEH, WF ;
TSAI, CT .
JOURNAL OF APPLIED PHYSICS, 1991, 69 (12) :8402-8404
[6]  
Contreras MA, 1999, PROG PHOTOVOLTAICS, V7, P311, DOI 10.1002/(SICI)1099-159X(199907/08)7:4<311::AID-PIP274>3.0.CO
[7]  
2-G
[8]   STRUCTURAL AND PHOTOLUMINESCENCE CHARACTERIZATION OF CDS/GAAS FILMS AND CDS-ZNS STRAINED-LAYER SUPERLATTICES GROWN BY LOW-PRESSURE MOCVD METHOD [J].
ENDOH, Y ;
KAWAKAMI, Y ;
TAGUCHI, T ;
HIRAKI, A .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1988, 27 (11) :L2199-L2202
[9]  
FROMENT M, 1995, J ELECTROCHEM SOC, V142, P2624
[10]   CDS MICROCRYSTALLITES DOPED THIN-FILM GLASS WAVE-GUIDES [J].
JEROMINEK, H ;
PIGEON, M ;
PATELA, S ;
JAKUBCZYK, Z ;
DELISLE, C ;
TREMBLAY, R .
JOURNAL OF APPLIED PHYSICS, 1988, 63 (03) :957-959